Advective–diffusive transport in microflows is studied by means of the diffusive mapping method, a recent extension of the mapping method by Gorodetskyi et al. (2012. Phys. Fluids 24) that includes molecular diffusion. This greatly expands the application area of the mapping technique and makes the powerful concepts of eigenmode decomposition and spectral analysis of scalar transport accessible to an important class of flows: inline micromixers with diffusion. The staggered herringbone micro-mixer is adopted as a prototypical three-dimensional micro mixer. Simulations with the diffusive mapping method are in close agreement with experimental observations in the literature and expose a strong impact of diffusion on the transport. Diffusion e...