The reaction of the Ph4P2N4S2R anions (R = Me or Bu(t)), generated from 1,5-Ph4P2N4S, and the appropriate alkyllithium reagent, with cis- or trans-[MCl2(PEt3)2] (M = Pd or Pt) produces the complexes [MCI(PEt3)2(Ph4P2N4S2R)] (R = Me, M = Pd or Pt; R = Bu(t), M = Pt) shown by X-ray crystallography (M = Pd, R = Me) to involve cy-S bonding of the P2N4S, ring to the metal; variable-temperature P-31 NMR spectra of these complexes indicate a significant energy barrier to rotation about the M-S bond of 41-46 kJ mol-1.</p
The reactions of M(pnp)Cl2 [M = Pd, Pt; pnp = 2,6-bis(diphenylphosphinomethyl)pyridine] and Pt(dppf)...
Two new complex salts of the form (Bu4N)(2)[Ni(L)(2)] (1) and (Ph4P)(2)[Ni(L)(2)] (2) and four heter...
Solutions containing unstable organopalladium(IV) complexes of phosphines, [PdMe3(bpy)(L)]+ (L = PMe...
The reaction of the Ph4P2N4S2R anions (R = Me or Bu(t)), generated from 1,5-Ph4P2N4S, and the approp...
The reaction of the Ph4P2N4S2R anions (R = Me or Bu(t)), generated from 1,5-Ph4P2N4S, and the approp...
The reaction of the Ph4P2N4S2R anions (R = Me or Bu(t)), generated from 1,5-Ph4P2N4S, and the approp...
The reaction of Pt(PPh3)2(C2H4) with 1,5-R4P2N4S2 (R = Ph, Et, Me) in toluene at 23-degrees-C produc...
The reaction of Pt(PPh3)2(C2H4) with 1,5-R4P2N4S2 (R = Ph, Et, Me) in toluene at 23-degrees-C produc...
The reaction of Pt(PPh3)2(C2H4) with 1,5-R4P2N4S2 (R = Ph, Et, Me) in toluene at 23-degrees-C produc...
The reaction of Pt(PPh3)2(C2H4) with 1,5-R4P2N4S2 (R = Ph, Et, Me) in toluene at 23-degrees-C produc...
Cyanomethyl(diphenyl)phosphine (L) and o-cyanopheryl(diphenyl)phosphine (LI) react with H2PdX4 (X = ...
The compound S4N4 reacts with [PPh4]2[Pd2X6] (X = Cl or Br) in CH2Cl2 to give a mixture of [PPh4]2[P...
Reaction of Me(3)SiNSNSNSNSiMe(3) with [PPh(4)](2)[Pd2Cl6] resulted in a mixture of [PPh(4)][PdCl2(S...
Reaction of PtCl2(cod) with Pr-2(i) P(S)NHP(S)Pr-2(i) gives [M{N(Pr-2(i) PS)(2)}(2)] (M = Pt 1, Pd 2...
Bis-triphenylphosphine and bis(diphenylphosphine)ethane platinum(II) complexes with the chelating an...
The reactions of M(pnp)Cl2 [M = Pd, Pt; pnp = 2,6-bis(diphenylphosphinomethyl)pyridine] and Pt(dppf)...
Two new complex salts of the form (Bu4N)(2)[Ni(L)(2)] (1) and (Ph4P)(2)[Ni(L)(2)] (2) and four heter...
Solutions containing unstable organopalladium(IV) complexes of phosphines, [PdMe3(bpy)(L)]+ (L = PMe...
The reaction of the Ph4P2N4S2R anions (R = Me or Bu(t)), generated from 1,5-Ph4P2N4S, and the approp...
The reaction of the Ph4P2N4S2R anions (R = Me or Bu(t)), generated from 1,5-Ph4P2N4S, and the approp...
The reaction of the Ph4P2N4S2R anions (R = Me or Bu(t)), generated from 1,5-Ph4P2N4S, and the approp...
The reaction of Pt(PPh3)2(C2H4) with 1,5-R4P2N4S2 (R = Ph, Et, Me) in toluene at 23-degrees-C produc...
The reaction of Pt(PPh3)2(C2H4) with 1,5-R4P2N4S2 (R = Ph, Et, Me) in toluene at 23-degrees-C produc...
The reaction of Pt(PPh3)2(C2H4) with 1,5-R4P2N4S2 (R = Ph, Et, Me) in toluene at 23-degrees-C produc...
The reaction of Pt(PPh3)2(C2H4) with 1,5-R4P2N4S2 (R = Ph, Et, Me) in toluene at 23-degrees-C produc...
Cyanomethyl(diphenyl)phosphine (L) and o-cyanopheryl(diphenyl)phosphine (LI) react with H2PdX4 (X = ...
The compound S4N4 reacts with [PPh4]2[Pd2X6] (X = Cl or Br) in CH2Cl2 to give a mixture of [PPh4]2[P...
Reaction of Me(3)SiNSNSNSNSiMe(3) with [PPh(4)](2)[Pd2Cl6] resulted in a mixture of [PPh(4)][PdCl2(S...
Reaction of PtCl2(cod) with Pr-2(i) P(S)NHP(S)Pr-2(i) gives [M{N(Pr-2(i) PS)(2)}(2)] (M = Pt 1, Pd 2...
Bis-triphenylphosphine and bis(diphenylphosphine)ethane platinum(II) complexes with the chelating an...
The reactions of M(pnp)Cl2 [M = Pd, Pt; pnp = 2,6-bis(diphenylphosphinomethyl)pyridine] and Pt(dppf)...
Two new complex salts of the form (Bu4N)(2)[Ni(L)(2)] (1) and (Ph4P)(2)[Ni(L)(2)] (2) and four heter...
Solutions containing unstable organopalladium(IV) complexes of phosphines, [PdMe3(bpy)(L)]+ (L = PMe...