Removing compositional boundaries in mixed-linker Keplerate clusters
- Botar, B.
- Ellern, A.
- Hermann, R.
- Kögerler, P.
Publication date
January 2009
DOI Publisher
Wiley ISSN
1434-1948 Citation count (estimate)
8Abstract
The formation of a self-assembled multi-heterometal Keplerate polyoxomolybdate demonstrates compositional control of linker groups in spherical clusters. The resulting partially reduced {(Mo72Fe20V8Mo2V)-Fe-V/VI-V-III-Mo-IV}-type cluster exhibits intramolecular ferrimagnetic ordering characteristic of such mixed-spin Keplerate systems. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009
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