A series of transition metal nitrite complexes have been prepared. These include tetranitrite complex ions of the formula [M(NO\(_2\))\(_4\)]\(^{2-}\), M = Zn(II), Cd(II) and Hg(II), a series of nickel(TT) nitrite complexes with amines of varying degrees of substitution and the pentammine nitrite complexes [Co(NH\(_3\))\(_5\)NO\(_2\)]\(^{2+}\), [Co(NH\(_3\))\(_5\)ONO]\(^{2+}\) and [Cr(NH\(_3\))\(_5\)ONO]\(^{2+}\). Single crystal optical spectra were measured for the Co(III), Cr(III) and Ni(II) complexes. The observed transition energies for these complexes are compared with those calculated using the Angular Overlap Model (AOM). Bonding parameters have been derived for the nitrite ligands, and the parameters are shown to be transferable t...
Institute of Chemical Sciences, Devi Ahilya University Indore, Khandwa Road, Post Box No. 105, Indor...
Nitrite coordination to heme cofactors is a key step in the anaerobic production of the signaling mo...
Author Institution: UMR7075 CNRS-P6, Universit\'e Pierre et Marie Curie; LAPDIR/Spectroschimie Mol\...
A series of transition metal nitrite complexes have been prepared. These include tetranitrite comple...
Four new nickel (II) complexes, [Ni2L2 (NO2)2]•CH2Cl2•C2H5OH, 2H2O (1), [Ni2L2(DMF)2(μ-NO2)]ClO...
Four new nickel(II) complexes, [Ni2L2(NO2)2]·CH2Cl2·C2H5OH, 2H2O (1), [Ni2L2(DMF)2(m-NO2)]ClO4·DMF (...
Department of Chemistry, Stanford University, Stanford, California 94805, U.S.A. The infrared frequ...
Single crystal photocrystallographic experiments and solid state Raman spectroscopy have been used t...
The ambidentate nitrite ion, NO2−, is a biologically relevant species that can be coordinated to tra...
The standard oxidation states of central metal atoms in C_(4v) nitrido ([M(N)(L)₅]^z) complexes are ...
Nitrite coordination to heme cofactors is a key step in the anaerobic production of the signaling mo...
International audienceThe coordination chemistry of the nitrite anion has been investigated with rar...
Nitride complexes have been invoked as catalysts and intermediates in a wide variety of transformati...
The nickel and zinc complexes of 2-aminomethylaniline (AMA) are reported. Both metals form the octah...
The reactivity of nitrite towards the copper(II) and copper(I) centers of a series of complexes wi...
Institute of Chemical Sciences, Devi Ahilya University Indore, Khandwa Road, Post Box No. 105, Indor...
Nitrite coordination to heme cofactors is a key step in the anaerobic production of the signaling mo...
Author Institution: UMR7075 CNRS-P6, Universit\'e Pierre et Marie Curie; LAPDIR/Spectroschimie Mol\...
A series of transition metal nitrite complexes have been prepared. These include tetranitrite comple...
Four new nickel (II) complexes, [Ni2L2 (NO2)2]•CH2Cl2•C2H5OH, 2H2O (1), [Ni2L2(DMF)2(μ-NO2)]ClO...
Four new nickel(II) complexes, [Ni2L2(NO2)2]·CH2Cl2·C2H5OH, 2H2O (1), [Ni2L2(DMF)2(m-NO2)]ClO4·DMF (...
Department of Chemistry, Stanford University, Stanford, California 94805, U.S.A. The infrared frequ...
Single crystal photocrystallographic experiments and solid state Raman spectroscopy have been used t...
The ambidentate nitrite ion, NO2−, is a biologically relevant species that can be coordinated to tra...
The standard oxidation states of central metal atoms in C_(4v) nitrido ([M(N)(L)₅]^z) complexes are ...
Nitrite coordination to heme cofactors is a key step in the anaerobic production of the signaling mo...
International audienceThe coordination chemistry of the nitrite anion has been investigated with rar...
Nitride complexes have been invoked as catalysts and intermediates in a wide variety of transformati...
The nickel and zinc complexes of 2-aminomethylaniline (AMA) are reported. Both metals form the octah...
The reactivity of nitrite towards the copper(II) and copper(I) centers of a series of complexes wi...
Institute of Chemical Sciences, Devi Ahilya University Indore, Khandwa Road, Post Box No. 105, Indor...
Nitrite coordination to heme cofactors is a key step in the anaerobic production of the signaling mo...
Author Institution: UMR7075 CNRS-P6, Universit\'e Pierre et Marie Curie; LAPDIR/Spectroschimie Mol\...