Single crystal photocrystallographic experiments and solid state Raman spectroscopy have been used to determine the low temperature, metastable structures of the nickel(II) nitrito complexes [Ni(aep)(2)(eta(1)-ONO) 2] 1#O (aep = 1-(2-aminoethyl) piperidine), [Ni(aem)(2)(eta(1)-ONO)(2)] 2#O (aem = 1-(2-aminoethyl)morpholine), and [Ni(aepy)(2)(eta(1)-ONO)(2)] 3#O (aepy = 1-(2-aminoethyl) pyrrolidine and where the #O denotes the oxygen-bound nitrito metastable molecule). These linkage isomers of the equivalent nitro complexes [Ni(aep)(2)(eta(1)-NO(2))(2)] 1, [Ni(aem)(2)(eta(1)-NO(2))(2)] 2 and [Ni(aepy)2(eta(1)-NO(2))(2)] 3 are formed by LED irradiation at temperatures below 120 K. The behavior of the three complexes upon irradiation is genera...
The complexes [NiL<sub>3</sub>](NO<sub>2</sub>)<sub>2</sub>•2H<sub>2</sub>O (violet, 1) and cis-[NiL...
Conspectus The design of solid-state materials whose properties and functions can be manipulated in ...
The [IrCl5NO]−1 ion in the potassium salt can be partially transformed into a metastable state by li...
Single crystal photocrystallographic experiments and solid state Raman spectroscopy have been used t...
The known complex [Ni(medpt)(η1-NO2)(η2-ONO)] 1 (medpt = 3,3′-diamino-N-methyldipropylamine) crystal...
One way or another: The N‐bound NO2 group in [Ni(Et4dien)(η2‐O,ON)(η1‐NO2)] (see structure Ni turquo...
The solid-state, low-temperature linkage isomerism in a series of five square planar group 10 phosph...
Abstract—New metastable species are formed by low-temperature irradiation of crystals of transition ...
The known complex [Ni(medpt)(η-1NO2) (η2-ONO)] 1 (medpt = 3,3′-diamino-N-methyldipropylamine) crysta...
‘Photocrystallography ’ is a rapidly developing technique that involves the deter-mination of the fu...
A simple mono-nuclear nickel(II) complex [NiII{C6H4(NH2)2}2(NO2)2] (1) has been synthesized from an ...
A series of transition metal nitrite complexes have been prepared. These include tetranitrite comple...
The linkage isomers trans-bis[1-(2-aminoethyl)piperidine]dinitronickel (II) (brown) 1 and trans-bis[...
Author Institution: UMR7075 CNRS-P6, Universit\'e Pierre et Marie Curie; LAPDIR/Spectroschimie Mol\...
At temperatures below 150 K, the photoactivated metastable endo‐nitrito linkage isomer [Ni(Et4dien)(...
The complexes [NiL<sub>3</sub>](NO<sub>2</sub>)<sub>2</sub>•2H<sub>2</sub>O (violet, 1) and cis-[NiL...
Conspectus The design of solid-state materials whose properties and functions can be manipulated in ...
The [IrCl5NO]−1 ion in the potassium salt can be partially transformed into a metastable state by li...
Single crystal photocrystallographic experiments and solid state Raman spectroscopy have been used t...
The known complex [Ni(medpt)(η1-NO2)(η2-ONO)] 1 (medpt = 3,3′-diamino-N-methyldipropylamine) crystal...
One way or another: The N‐bound NO2 group in [Ni(Et4dien)(η2‐O,ON)(η1‐NO2)] (see structure Ni turquo...
The solid-state, low-temperature linkage isomerism in a series of five square planar group 10 phosph...
Abstract—New metastable species are formed by low-temperature irradiation of crystals of transition ...
The known complex [Ni(medpt)(η-1NO2) (η2-ONO)] 1 (medpt = 3,3′-diamino-N-methyldipropylamine) crysta...
‘Photocrystallography ’ is a rapidly developing technique that involves the deter-mination of the fu...
A simple mono-nuclear nickel(II) complex [NiII{C6H4(NH2)2}2(NO2)2] (1) has been synthesized from an ...
A series of transition metal nitrite complexes have been prepared. These include tetranitrite comple...
The linkage isomers trans-bis[1-(2-aminoethyl)piperidine]dinitronickel (II) (brown) 1 and trans-bis[...
Author Institution: UMR7075 CNRS-P6, Universit\'e Pierre et Marie Curie; LAPDIR/Spectroschimie Mol\...
At temperatures below 150 K, the photoactivated metastable endo‐nitrito linkage isomer [Ni(Et4dien)(...
The complexes [NiL<sub>3</sub>](NO<sub>2</sub>)<sub>2</sub>•2H<sub>2</sub>O (violet, 1) and cis-[NiL...
Conspectus The design of solid-state materials whose properties and functions can be manipulated in ...
The [IrCl5NO]−1 ion in the potassium salt can be partially transformed into a metastable state by li...