Much has been said but little settled about the precise nature of the Grignard reagent. The X-ray structure studies of Stucky and Rundle, the vapor pressure studies of Vreugdenhil and Blomberg, the work of Ashby and Becker and the far-infrared experiments of Salinger and Mosher all indicate that the Grignard reagent can exist, at least in part, as a monomer (RMg-X) under a variety of experimental conditions
Grignard Compounds RMgX (R=organic group ; X=Cl, Br, I) are common tools in inorganic and organic sy...
In the presence of transition metal chloride and potassium iodide, di-Grignard reagents can be produ...
Summary: A technique for obtaining relative rates of reaction of organic halides with metallic magne...
Much has been said but little settled about the precise nature of the Grignard reagent. The X-ray st...
The Grignard compounds MeMgBr and EtMgBr in n-Bu2O were studied at room temperature and — 85°C by ex...
A Grignard reagent is commonly represented by the formula RMgX. It has been established, however, th...
The structure of the dimeric ethylmagnesium bromide/diisopropyl ether complex [C2H5MgBr - O(i-C3H7)2...
The results of an EXAFS study of the Grignard compounds methyl, ethyl and phenyl magnesium bromide i...
In connection with our work on the nature of the butenyl Grigiiard reagent it was desirable to study...
Author Institution: Department of Chemistry, University of VirginiaMagnesium atoms were generated by...
Examples of Grignard reagents obtained by C-F bond activation with magnesium have kept appearing in ...
Crotyl bromide and α-methylallyl bromide each react with magnesium in ether to yield the same buteny...
Abstract: The rate of reaction of organic halides with magnesium is proportional to organic halide c...
Studies have been made of the nuclear magnetic resonance spectra of several allylic Grignard reagen...
1. Y. Imuzu, and K.J. Klabunde, Inorgan, Chem, 23, 3602 (1984) 2. B.S. Ault. JACS 102, 3480 (1980) 3...
Grignard Compounds RMgX (R=organic group ; X=Cl, Br, I) are common tools in inorganic and organic sy...
In the presence of transition metal chloride and potassium iodide, di-Grignard reagents can be produ...
Summary: A technique for obtaining relative rates of reaction of organic halides with metallic magne...
Much has been said but little settled about the precise nature of the Grignard reagent. The X-ray st...
The Grignard compounds MeMgBr and EtMgBr in n-Bu2O were studied at room temperature and — 85°C by ex...
A Grignard reagent is commonly represented by the formula RMgX. It has been established, however, th...
The structure of the dimeric ethylmagnesium bromide/diisopropyl ether complex [C2H5MgBr - O(i-C3H7)2...
The results of an EXAFS study of the Grignard compounds methyl, ethyl and phenyl magnesium bromide i...
In connection with our work on the nature of the butenyl Grigiiard reagent it was desirable to study...
Author Institution: Department of Chemistry, University of VirginiaMagnesium atoms were generated by...
Examples of Grignard reagents obtained by C-F bond activation with magnesium have kept appearing in ...
Crotyl bromide and α-methylallyl bromide each react with magnesium in ether to yield the same buteny...
Abstract: The rate of reaction of organic halides with magnesium is proportional to organic halide c...
Studies have been made of the nuclear magnetic resonance spectra of several allylic Grignard reagen...
1. Y. Imuzu, and K.J. Klabunde, Inorgan, Chem, 23, 3602 (1984) 2. B.S. Ault. JACS 102, 3480 (1980) 3...
Grignard Compounds RMgX (R=organic group ; X=Cl, Br, I) are common tools in inorganic and organic sy...
In the presence of transition metal chloride and potassium iodide, di-Grignard reagents can be produ...
Summary: A technique for obtaining relative rates of reaction of organic halides with metallic magne...