The results of an EXAFS study of the Grignard compounds methyl, ethyl and phenyl magnesium bromide in diethyl ether and vinyl magnesium bromide in tetrahydrofuran are presented in this paper. The degree of molecular association and the local structure around the central magnesium atoms are deduced from the determined distances and coordination number
Crotyl bromide and α-methylallyl bromide each react with magnesium in ether to yield the same buteny...
Abstract: The rate of reaction of organic halides with magnesium is proportional to organic halide c...
Despite considerable efforts being given to organometallic complexes of lithium and magnesium (Grign...
The Grignard compounds MeMgBr and EtMgBr in n-Bu2O were studied at room temperature and — 85°C by ex...
Grignard Compounds RMgX (R=organic group ; X=Cl, Br, I) are common tools in inorganic and organic sy...
Much has been said but little settled about the precise nature of the Grignard reagent. The X-ray st...
The structure of the dimeric ethylmagnesium bromide/diisopropyl ether complex [C2H5MgBr - O(i-C3H7)2...
1. Y. Imuzu, and K.J. Klabunde, Inorgan, Chem, 23, 3602 (1984) 2. B.S. Ault. JACS 102, 3480 (1980) 3...
Author Institution: Department of Chemistry, University of VirginiaMagnesium atoms were generated by...
The composition of Grignard reagents has been studied extensively by nuclear magnetic resonance spec...
The investigations of Grignard compounds are very instructive for understanding the principles of ge...
Examples of Grignard reagents obtained by C-F bond activation with magnesium have kept appearing in ...
R factor = 0.031; wR factor = 0.073; data-to-parameter ratio = 18.6. The title benzyl Grignard reage...
Since their discovery, the exact solution composition of Grignard compounds has been the subject of ...
In connection with our work on the nature of the butenyl Grigiiard reagent it was desirable to study...
Crotyl bromide and α-methylallyl bromide each react with magnesium in ether to yield the same buteny...
Abstract: The rate of reaction of organic halides with magnesium is proportional to organic halide c...
Despite considerable efforts being given to organometallic complexes of lithium and magnesium (Grign...
The Grignard compounds MeMgBr and EtMgBr in n-Bu2O were studied at room temperature and — 85°C by ex...
Grignard Compounds RMgX (R=organic group ; X=Cl, Br, I) are common tools in inorganic and organic sy...
Much has been said but little settled about the precise nature of the Grignard reagent. The X-ray st...
The structure of the dimeric ethylmagnesium bromide/diisopropyl ether complex [C2H5MgBr - O(i-C3H7)2...
1. Y. Imuzu, and K.J. Klabunde, Inorgan, Chem, 23, 3602 (1984) 2. B.S. Ault. JACS 102, 3480 (1980) 3...
Author Institution: Department of Chemistry, University of VirginiaMagnesium atoms were generated by...
The composition of Grignard reagents has been studied extensively by nuclear magnetic resonance spec...
The investigations of Grignard compounds are very instructive for understanding the principles of ge...
Examples of Grignard reagents obtained by C-F bond activation with magnesium have kept appearing in ...
R factor = 0.031; wR factor = 0.073; data-to-parameter ratio = 18.6. The title benzyl Grignard reage...
Since their discovery, the exact solution composition of Grignard compounds has been the subject of ...
In connection with our work on the nature of the butenyl Grigiiard reagent it was desirable to study...
Crotyl bromide and α-methylallyl bromide each react with magnesium in ether to yield the same buteny...
Abstract: The rate of reaction of organic halides with magnesium is proportional to organic halide c...
Despite considerable efforts being given to organometallic complexes of lithium and magnesium (Grign...
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