The structure of the dimeric ethylmagnesium bromide/diisopropyl ether complex [C2H5MgBr - O(i-C3H7)2]2 was studied with s ingle crystal X-ray diffraction techniques. Crystals are monoclinic with spacegroup P21/n and two dimers per unit cell of dimensions a 7.85(1), b 14.43(2), c 11,31(2) °A, β 100.3(1)o The structure was refined to a final R-value of 0.073. The magnesium is four coordinate; dimers are formed through bridging bromine atoms. p]This result is briefly discussed in the context of factors governing complex formation of Grignard reagents
The crystal structure of dibromamine-T, an important brominating/oxidising agent, which crystallizes...
The Hauser base reagents Pri2NMgCl 1 and Pri2NMgBr 2 react with a variety of enolisable ketones to y...
Chelating alkali metal amides derived from metallation of the secondary amines PhCH2(Me2NCH2CH2)NH a...
R factor = 0.031; wR factor = 0.073; data-to-parameter ratio = 18.6. The title benzyl Grignard reage...
The title benzyl Grignard reagent, [Mg2Br2(C7H7)2(C4H10O)2], was obtained by reaction of benzyl brom...
Much has been said but little settled about the precise nature of the Grignard reagent. The X-ray st...
A neutral dimeric molecule in crystal form, the diisopropylamido turbo-Grignard reagent '(iPr2N)MgCl...
The crystal structure of the title compound, [Mg2Br2(C9H11)2(C4H10O)2], features a centrosymmetric t...
Jutzi P, KLEIMEIER J, REDEKER T, Stammler H-G, NEUMANN B. SYNTHESIS, STRUCTURE AND PROPERTIES OF GRI...
Crotyl bromide and α-methylallyl bromide each react with magnesium in ether to yield the same buteny...
The results of an EXAFS study of the Grignard compounds methyl, ethyl and phenyl magnesium bromide i...
The solid-state structure of a dimeric β-diketiminate magnesium(II) complex is discussed. The compou...
The Grignard compounds MeMgBr and EtMgBr in n-Bu2O were studied at room temperature and — 85°C by ex...
The work reported by D. Bryce-Smith and G. F. Cox, along with several recent publications describing...
The coordination geometry at the Mg atom in the title complex, [MgBrz{(C3Hv)2NH}{(C2Hs)20}], is show...
The crystal structure of dibromamine-T, an important brominating/oxidising agent, which crystallizes...
The Hauser base reagents Pri2NMgCl 1 and Pri2NMgBr 2 react with a variety of enolisable ketones to y...
Chelating alkali metal amides derived from metallation of the secondary amines PhCH2(Me2NCH2CH2)NH a...
R factor = 0.031; wR factor = 0.073; data-to-parameter ratio = 18.6. The title benzyl Grignard reage...
The title benzyl Grignard reagent, [Mg2Br2(C7H7)2(C4H10O)2], was obtained by reaction of benzyl brom...
Much has been said but little settled about the precise nature of the Grignard reagent. The X-ray st...
A neutral dimeric molecule in crystal form, the diisopropylamido turbo-Grignard reagent '(iPr2N)MgCl...
The crystal structure of the title compound, [Mg2Br2(C9H11)2(C4H10O)2], features a centrosymmetric t...
Jutzi P, KLEIMEIER J, REDEKER T, Stammler H-G, NEUMANN B. SYNTHESIS, STRUCTURE AND PROPERTIES OF GRI...
Crotyl bromide and α-methylallyl bromide each react with magnesium in ether to yield the same buteny...
The results of an EXAFS study of the Grignard compounds methyl, ethyl and phenyl magnesium bromide i...
The solid-state structure of a dimeric β-diketiminate magnesium(II) complex is discussed. The compou...
The Grignard compounds MeMgBr and EtMgBr in n-Bu2O were studied at room temperature and — 85°C by ex...
The work reported by D. Bryce-Smith and G. F. Cox, along with several recent publications describing...
The coordination geometry at the Mg atom in the title complex, [MgBrz{(C3Hv)2NH}{(C2Hs)20}], is show...
The crystal structure of dibromamine-T, an important brominating/oxidising agent, which crystallizes...
The Hauser base reagents Pri2NMgCl 1 and Pri2NMgBr 2 react with a variety of enolisable ketones to y...
Chelating alkali metal amides derived from metallation of the secondary amines PhCH2(Me2NCH2CH2)NH a...