Cp'TiCl3 (1; Cp' = eta-5-C5Me4(CH2)3OMe) reacts with 2 equiv of the phosphorous ylide PPh3 = CH2 (2) to yield Cp'TiCl2(CHPPh3) (3) plus the phosphonium salt (MePPh3)Cl. Complex 3 decomposes thermally to give [eta-5:eta-1-C5Me4(CH2)3O]TiCl2 (4), containing a Cp* -alkoxide-functionalized ligand. The molecular structure of 4 shows it as a pseudo three-legged piano-stool complex
[Ti(η5-C5H5)Cl3] reacts with Me3Si—N=N—Ph to give [Ti(η5-C5H5)Cl2(N2Ph)], and this gives [Ti(η5-C5H5...
Compounds (η5-C5H4CH2CH2OCH3)TiCl3, (η5-C5H4CH2CH2OCH3)2TiCl2 and (η5-C5H4CH2CH2OCH3)(η5-C5H5)TiCl2 ...
Much attention has been given to Group 4 metal compounds containing either bis(cyclopentadienyl) or ...
Cp'TiCl3 (1; Cp' = eta-5-C5Me4(CH2)3OMe) reacts with 2 equiv of the phosphorous ylide PPh3 = CH2 (2)...
Cp'TiCl3 (1; Cp’ = η5-C5Me4CH2)3OMe) reacts with 2 equiv of the phosphorous ylide PPh3=CH2 (2) to yi...
Reaction of C5R41(SiMe3)(CHRCH2CRROR5)-C-2-R-3-O-4 with titanium tetrachloride gives the bidentate e...
Trimethylsilylcyclopentadiene-siloxy ethers Me(3)SiC(5)H(4)(CH2),OSiMe(3) (n = 2, 3) react with TiCl...
Trimethylsilylcyclopentadiene-siloxy ethers Me(3)SiC(5)H(4)(CH2),OSiMe(3) (n = 2, 3) react with TiCl...
Reaction of C5R14 (SiMe3)CHR2CH2CR3CR4OR5 with titanium tetrachloride gives bidentate (η5, &sigm...
The titanium complexes [η5:η1-C5Me4(CH2)3O]TiR2 (R = Cl, Me, CH2Ph, CH2CMe3, CH2SiMe3), with a linke...
The titanium complexes [η5:η1-C5Me4(CH2)3O]TiR2 (R = Cl, Me, CH2Ph, CH2CMe3, CH2SiMe3), with a linke...
The titanium complexes [η5:η1-C5Me4(CH2)3O]TiR2 (R = Cl, Me, CH2Ph, CH2CMe3, CH2SiMe3), with a linke...
The (borylcyclopentadienyl)titanium complex (Cp-B)TiCl3 (1; Cp-B = eta(5)-C5H4B(C6F5)(2)) reacts wit...
Three substituted cyclopentadienyl titanium(III) complexes with intramolecular amino group coordinat...
We report the chemical behaviour of pentamethylcyclopentadienyl titanium alkyls and oxo-alkyls. CpxT...
[Ti(η5-C5H5)Cl3] reacts with Me3Si—N=N—Ph to give [Ti(η5-C5H5)Cl2(N2Ph)], and this gives [Ti(η5-C5H5...
Compounds (η5-C5H4CH2CH2OCH3)TiCl3, (η5-C5H4CH2CH2OCH3)2TiCl2 and (η5-C5H4CH2CH2OCH3)(η5-C5H5)TiCl2 ...
Much attention has been given to Group 4 metal compounds containing either bis(cyclopentadienyl) or ...
Cp'TiCl3 (1; Cp' = eta-5-C5Me4(CH2)3OMe) reacts with 2 equiv of the phosphorous ylide PPh3 = CH2 (2)...
Cp'TiCl3 (1; Cp’ = η5-C5Me4CH2)3OMe) reacts with 2 equiv of the phosphorous ylide PPh3=CH2 (2) to yi...
Reaction of C5R41(SiMe3)(CHRCH2CRROR5)-C-2-R-3-O-4 with titanium tetrachloride gives the bidentate e...
Trimethylsilylcyclopentadiene-siloxy ethers Me(3)SiC(5)H(4)(CH2),OSiMe(3) (n = 2, 3) react with TiCl...
Trimethylsilylcyclopentadiene-siloxy ethers Me(3)SiC(5)H(4)(CH2),OSiMe(3) (n = 2, 3) react with TiCl...
Reaction of C5R14 (SiMe3)CHR2CH2CR3CR4OR5 with titanium tetrachloride gives bidentate (η5, &sigm...
The titanium complexes [η5:η1-C5Me4(CH2)3O]TiR2 (R = Cl, Me, CH2Ph, CH2CMe3, CH2SiMe3), with a linke...
The titanium complexes [η5:η1-C5Me4(CH2)3O]TiR2 (R = Cl, Me, CH2Ph, CH2CMe3, CH2SiMe3), with a linke...
The titanium complexes [η5:η1-C5Me4(CH2)3O]TiR2 (R = Cl, Me, CH2Ph, CH2CMe3, CH2SiMe3), with a linke...
The (borylcyclopentadienyl)titanium complex (Cp-B)TiCl3 (1; Cp-B = eta(5)-C5H4B(C6F5)(2)) reacts wit...
Three substituted cyclopentadienyl titanium(III) complexes with intramolecular amino group coordinat...
We report the chemical behaviour of pentamethylcyclopentadienyl titanium alkyls and oxo-alkyls. CpxT...
[Ti(η5-C5H5)Cl3] reacts with Me3Si—N=N—Ph to give [Ti(η5-C5H5)Cl2(N2Ph)], and this gives [Ti(η5-C5H5...
Compounds (η5-C5H4CH2CH2OCH3)TiCl3, (η5-C5H4CH2CH2OCH3)2TiCl2 and (η5-C5H4CH2CH2OCH3)(η5-C5H5)TiCl2 ...
Much attention has been given to Group 4 metal compounds containing either bis(cyclopentadienyl) or ...