Cyclopentadienyl Titanium Complexes with Aryldiazenido- or Phosphiniminato-ligands

Dilworth, J.R.,
Liefde Meijer, H.J. de,
Teuben, J.H.,

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Publication date

January 1978

DOI

10.1016/s0022-328x(00)80879-7

ISSN

0022-328X

Abstract

[Ti(η5-C5H5)Cl3] reacts with Me3Si—N=N—Ph to give [Ti(η5-C5H5)Cl2(N2Ph)], and this gives [Ti(η5-C5H5)2Cl(N2Ph)] on treatment with sodium cyclopentadienide in THF at —80°C. [Ti(η5-C5H4R)Cl3] (R = H, Me) reacts analogously with Me3Si—N=PR3 (PR3 = PPh3, PPh2Me) to give [Ti(η5-C5H4R)Cl2(NPR3)]. Under similar conditions TiCl4 gives [TiCl4(Me3SiNPR3)].

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Cyclopentadienyl Titanium Complexes with Aryldiazenido- or Phosphiniminato-ligands

Abstract

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Cyclopentadienyl Titanium Complexes with Aryldiazenido- or Phosphiniminato-ligands

Abstract

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