Photoassisted Oxidation of Sulfides Catalyzed by Artificial Metalloenzymes Using Water as an Oxygen Source †
- Christian Herrero
- Nhung Nguyen-Thi
- Fabien Hammerer
- Frédéric Banse
- Donald Gagné
- Nicolas Doucet
- Jean-Pierre Mahy
- Rémy Ricoux
Publication date
December 2016
DOI Publisher
MDPI AG ISSN
2073-4344 Journal
issn:2073-4344 Citation count (estimate)
1Abstract
The Mn(TpCPP)-Xln10A artificial metalloenzyme, obtained by non-covalent insertion of Mn(III)-meso-tetrakis(p-carboxyphenyl)porphyrin [Mn(TpCPP), 1-Mn] into xylanase 10A from Streptomyces lividans (Xln10A) as a host protein, was found able to catalyze the selective photo-induced oxidation of organic substrates in the presence of [RuII(bpy)3]2+ as a photosensitizer and [CoIII(NH3)5Cl]2+ as a sacrificial electron acceptor, using water as oxygen atom source
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