The Mn(TpCPP)-Xln10A artificial metalloenzyme, obtained by non-covalent insertion of Mn(III)-meso-tetrakis(p-carboxyphenyl)porphyrin [Mn(TpCPP), 1-Mn] into xylanase 10A from Streptomyces lividans (Xln10A) as a host protein, was found able to catalyze the selective photo-induced oxidation of organic substrates in the presence of [RuII(bpy)3] 2+ as a photosensitizer and [CoIII(NH3)5Cl]2+ as a sacrificial electron acceptor, using water as oxygen atom source
A salophen cobalt(II) complex enables water oxidation at neutral pH in photoactivated sacrificial c...
A presentation of this work was named a winner of the Meek Undergraduate Poster Session in 2009.In t...
The photoinduced splitting of water into hydrogen and oxygen has evoked great interest in recent yea...
The Mn(TpCPP)-Xln10A artificial metalloenzyme, obtained by non-covalent insertion of Mn(III)-meso-te...
International audienceThe Mn(TpCPP)-Xln10A artificial metalloenzyme, obtained by non-covalent insert...
International audienceThe Mn(TpCPP)-Xln10A artificial metalloenzyme, obtained by non-covalent insert...
The Mn(TpCPP)-Xln10A artificial metalloenzyme, obtained by non-covalent insertion of Mn(III)-meso-te...
The Mn(TpCPP)-Xln10A artificial metalloenzyme, obtained by non-covalent insertion of Mn(III)-meso-te...
Catalytic oxidation plays a crucial role in current chemical and pharmaceutical industries which is ...
note: Some notation in this abstract may not appear exactly as formatted in the thesis. In this wor...
Numerous transition metal catalysts have been designed as biomimetic model compounds for the active ...
hoto-induced oxidation-enhancement in biomimetic bridged Ru(II)–Mo(VI) photo-catalyst is unexpectedl...
International audienceHere we report the best artificial metalloenzyme to date for the selective oxi...
High-valent transition metal-oxo intermediates are of fundamental importance because of their centra...
Photo-induced oxidation-enhancement in biomimetic bridged Ru(II)–Mo(VI) photo-catalyst is unexpected...
A salophen cobalt(II) complex enables water oxidation at neutral pH in photoactivated sacrificial c...
A presentation of this work was named a winner of the Meek Undergraduate Poster Session in 2009.In t...
The photoinduced splitting of water into hydrogen and oxygen has evoked great interest in recent yea...
The Mn(TpCPP)-Xln10A artificial metalloenzyme, obtained by non-covalent insertion of Mn(III)-meso-te...
International audienceThe Mn(TpCPP)-Xln10A artificial metalloenzyme, obtained by non-covalent insert...
International audienceThe Mn(TpCPP)-Xln10A artificial metalloenzyme, obtained by non-covalent insert...
The Mn(TpCPP)-Xln10A artificial metalloenzyme, obtained by non-covalent insertion of Mn(III)-meso-te...
The Mn(TpCPP)-Xln10A artificial metalloenzyme, obtained by non-covalent insertion of Mn(III)-meso-te...
Catalytic oxidation plays a crucial role in current chemical and pharmaceutical industries which is ...
note: Some notation in this abstract may not appear exactly as formatted in the thesis. In this wor...
Numerous transition metal catalysts have been designed as biomimetic model compounds for the active ...
hoto-induced oxidation-enhancement in biomimetic bridged Ru(II)–Mo(VI) photo-catalyst is unexpectedl...
International audienceHere we report the best artificial metalloenzyme to date for the selective oxi...
High-valent transition metal-oxo intermediates are of fundamental importance because of their centra...
Photo-induced oxidation-enhancement in biomimetic bridged Ru(II)–Mo(VI) photo-catalyst is unexpected...
A salophen cobalt(II) complex enables water oxidation at neutral pH in photoactivated sacrificial c...
A presentation of this work was named a winner of the Meek Undergraduate Poster Session in 2009.In t...
The photoinduced splitting of water into hydrogen and oxygen has evoked great interest in recent yea...