Landau theory for biaxial nematic liquid crystals with two order parameter tensors

We present a phenomenological theory for the homogeneous phases of nematic liquid crystals constituted by biaxial molecules. We propose a general polynomial potential in two macroscopic order parameter tensors that reproduces the mean-field phase diagram confirmed by Monte Carlo simulations [De Matteis et al. in Phys Rev E 72:041706 (2005)] and recently recognized to be universal [Bisi et al. in Phys Rev E 73:051709 (2006)] for dispersion force molecular pair-potentials enjoying the D 2h symmetry. The requirement that the phenomenological theory comply uniquely with this phase diagram reduces considerably the admissible phenomenological coefficients, both in their number and in the ranges where they can vary