The new dialkyl(aryl) lithium zincates [(THF)2Li(C6H4−OMe)MeZnMe] (4), [(TMEDA)Li(C6H4−OMe)MeZnMe] (6), [(THF)3Li(C6H4−OMe)tBuZntBu] (7), and [(PMDETA)Li(C6H4−OMe)tBuZntBu] (8) have been prepared by co-complexation reactions of lithiated anisole with the relevant dialkylzinc compound and the relevant Lewis base. These new heterobimetallic compounds have been characterized in solution using 1H, 13C{H}, and 7Li NMR spectroscopy, and the molecular structures of 6 and 8 have been elucidated by X-ray crystallography. In 6 the distinct metals are connected through the anisole ligand which binds in an ambidentate fashion (through carbon−zinc and oxygen−lithium contacts) and also through one of the methyl groups, to close a [LiOCCZnC] six-membered ...
Novel homo- and heteroleptic lithium zincates have been prepared by cocomplexation reactions of Zn(C...
In a study aimed at developing the diisopropylamido (DA) chemistry of zincates, the new lithium DA-z...
In a study aimed at developing the diisopropylamido (DA) chemistry of zincates, the new lithium DA-z...
The new dialkyl(aryl) lithium zincates [(THF)2Li(C6H4−OMe)MeZnMe] (4), [(TMEDA)Li(C6H4−OMe)MeZnMe] (...
The new dialkyl(aryl) lithium zincates [(THF)2Li(C6H4−OMe)MeZnMe] (4), [(TMEDA)Li(C6H4−OMe)MeZnMe] (...
The new dialkyl(aryl) lithium zincates [(THF)2Li(C6H4−OMe)MeZnMe] (4), [(TMEDA)Li(C6H4−OMe)MeZnMe] (...
The new dialkyl(aryl) lithium zincates [(THF)2Li(C6H4−OMe)MeZnMe] (4), [(TMEDA)Li(C6H4−OMe)MeZnMe] (...
The new dialkyl(aryl) lithium zincates [(THF)2Li(C6H4−OMe)MeZnMe] (4), [(TMEDA)Li(C6H4−OMe)MeZnMe] (...
The new dialkyl(aryl) lithium zincates [(THF)<sub>2</sub>Li(C<sub>6</sub>H<sub>4</sub>−OMe)MeZnMe] (...
The new dialkyl(aryl) lithium zincates [(THF)<sub>2</sub>Li(C<sub>6</sub>H<sub>4</sub>−OMe)MeZnMe] (...
The new concept of alkali-metal-mediated zincation (AMMZ), formally a zinc−hydrogen exchange reactio...
The new concept of alkali-metal-mediated zincation (AMMZ), formally a zinc−hydrogen exchange reactio...
The new concept of alkali-metal-mediated zincation (AMMZ), formally a zinc−hydrogen exchange reactio...
Novel homo- and heteroleptic lithium zincates have been prepared by cocomplexation reactions of Zn(C...
Novel homo- and heteroleptic lithium zincates have been prepared by cocomplexation reactions of Zn(C...
Novel homo- and heteroleptic lithium zincates have been prepared by cocomplexation reactions of Zn(C...
In a study aimed at developing the diisopropylamido (DA) chemistry of zincates, the new lithium DA-z...
In a study aimed at developing the diisopropylamido (DA) chemistry of zincates, the new lithium DA-z...
The new dialkyl(aryl) lithium zincates [(THF)2Li(C6H4−OMe)MeZnMe] (4), [(TMEDA)Li(C6H4−OMe)MeZnMe] (...
The new dialkyl(aryl) lithium zincates [(THF)2Li(C6H4−OMe)MeZnMe] (4), [(TMEDA)Li(C6H4−OMe)MeZnMe] (...
The new dialkyl(aryl) lithium zincates [(THF)2Li(C6H4−OMe)MeZnMe] (4), [(TMEDA)Li(C6H4−OMe)MeZnMe] (...
The new dialkyl(aryl) lithium zincates [(THF)2Li(C6H4−OMe)MeZnMe] (4), [(TMEDA)Li(C6H4−OMe)MeZnMe] (...
The new dialkyl(aryl) lithium zincates [(THF)2Li(C6H4−OMe)MeZnMe] (4), [(TMEDA)Li(C6H4−OMe)MeZnMe] (...
The new dialkyl(aryl) lithium zincates [(THF)<sub>2</sub>Li(C<sub>6</sub>H<sub>4</sub>−OMe)MeZnMe] (...
The new dialkyl(aryl) lithium zincates [(THF)<sub>2</sub>Li(C<sub>6</sub>H<sub>4</sub>−OMe)MeZnMe] (...
The new concept of alkali-metal-mediated zincation (AMMZ), formally a zinc−hydrogen exchange reactio...
The new concept of alkali-metal-mediated zincation (AMMZ), formally a zinc−hydrogen exchange reactio...
The new concept of alkali-metal-mediated zincation (AMMZ), formally a zinc−hydrogen exchange reactio...
Novel homo- and heteroleptic lithium zincates have been prepared by cocomplexation reactions of Zn(C...
Novel homo- and heteroleptic lithium zincates have been prepared by cocomplexation reactions of Zn(C...
Novel homo- and heteroleptic lithium zincates have been prepared by cocomplexation reactions of Zn(C...
In a study aimed at developing the diisopropylamido (DA) chemistry of zincates, the new lithium DA-z...
In a study aimed at developing the diisopropylamido (DA) chemistry of zincates, the new lithium DA-z...