2-Butene has been found to react with oxygen at temperatures of 375° to 500°. At the higher temperatures, polymerization as well as oxidation takes place. The products of the reaction which have been identified are acetaldehyde, glyoxal and/or glycollic aldehyde, 1,3-butadiene, acid, peroxide and an olefin oxide. The simplest explanation of the reactions occurring involve both hydroxylation and peroxide formation as primary products
A stirred flow reactor was adapted to study the rate of formation of hydrocarbons in the low pressur...
Previous work show- that heptane and isooctane not only cliffered greatly in respect to their suscep...
A detailed chemical kinetic mechanism has been developed to describe the oxidation of small hydrocar...
2-Butene has been found to react with oxygen at temperatures of 375° to 500°. At the higher tempera...
In the first part of this work, the reaction between cis- and trans-2-butenes and oxygen atoms was s...
The thesis describes an investigation of the gas phase oxidation of the lower aliphatic ...
International audienceThe mechanism of the gas-phase reaction of OH radicals with hydroxyacetone (CH...
Previous work has shown that the branching ratio of the reaction of OH/C2H2/O2 to glyoxal and formic...
A study has been made of the pyrolysis of 1,5-hexadiene (diallyl) and of the reactions of the allyl ...
Alkyl-substituted cyclic ethers are intermediates formed in abundance during the low-temperature oxi...
The reaction of O-2 with butyl radicals is a key early step in the oxidation of n-butane, which is a...
A series of experiments were conducted which focused on understanding the role that the O atom addit...
Kinetic and mechanistic analysis shows that toluene and p-xylene produce after addition of OH by rea...
Ozonolysis reactions of alkenes are important oxidation pathways of alkenes in the atmosphere, and t...
The oxidation of 4-t-butyltoluene in glacial acetic acid by hydrogen peroxide in a process catalysed...
A stirred flow reactor was adapted to study the rate of formation of hydrocarbons in the low pressur...
Previous work show- that heptane and isooctane not only cliffered greatly in respect to their suscep...
A detailed chemical kinetic mechanism has been developed to describe the oxidation of small hydrocar...
2-Butene has been found to react with oxygen at temperatures of 375° to 500°. At the higher tempera...
In the first part of this work, the reaction between cis- and trans-2-butenes and oxygen atoms was s...
The thesis describes an investigation of the gas phase oxidation of the lower aliphatic ...
International audienceThe mechanism of the gas-phase reaction of OH radicals with hydroxyacetone (CH...
Previous work has shown that the branching ratio of the reaction of OH/C2H2/O2 to glyoxal and formic...
A study has been made of the pyrolysis of 1,5-hexadiene (diallyl) and of the reactions of the allyl ...
Alkyl-substituted cyclic ethers are intermediates formed in abundance during the low-temperature oxi...
The reaction of O-2 with butyl radicals is a key early step in the oxidation of n-butane, which is a...
A series of experiments were conducted which focused on understanding the role that the O atom addit...
Kinetic and mechanistic analysis shows that toluene and p-xylene produce after addition of OH by rea...
Ozonolysis reactions of alkenes are important oxidation pathways of alkenes in the atmosphere, and t...
The oxidation of 4-t-butyltoluene in glacial acetic acid by hydrogen peroxide in a process catalysed...
A stirred flow reactor was adapted to study the rate of formation of hydrocarbons in the low pressur...
Previous work show- that heptane and isooctane not only cliffered greatly in respect to their suscep...
A detailed chemical kinetic mechanism has been developed to describe the oxidation of small hydrocar...
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