Encapsulated nanowires : boosting electronic transport in carbon nanotubes

The electrical conductivity of metallic carbon nanotubes (CNTs) quickly saturates with respect to bias voltage due to scattering from a large population of optical phonons. The decay of these dominant scatterers in pristine CNTs is too slow to offset an increased generation rate at high voltage bias. We demonstrate from first principles that encapsulation of one-dimensional atomic chains within a single-walled CNT can enhance the decay of “hot” phonons by providing additional channels for thermalization. Pacification of the phonon population growth reduces the electrical resistivity of metallic CNTs by 51% for an example system with encapsulated beryllium