Zigzag HgTe nanowires modify the electron–phonon interaction in chirality-refined single-walled carbon nanotubes
- Hu, Ziyi
- Breeze, Ben
- Kashtiban, Reza J.
- Sloan, Jeremy
- Lloyd-Hughes, James
DOIAbstract
Atomically thin nanowires (NWs) can be synthesized inside single-walled carbon nanotubes (SWCNTs) and feature unique crystal structures. Here we show that HgTe nanowires formed inside small-diameter (<1 nm) SWCNTs can advantageously alter the optical and electronic properties of the SWCNTs. Metallic purification of the filled SWCNTs was achieved by a gel column chromatography method, leading to an efficient extraction of the semiconducting and metallic portions with known chiralities. Electron microscopic imaging revealed that zigzag HgTe chains were the dominant NW geometry in both the semiconducting and metallic species. Equilibrium-state and ultrafast spectroscopy demonstrated that the coupled electron–phonon system was modified by the e...
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