Author Institution: North American Aviation Science CenterA vibrational analysis of both $HBF_{2}$ and $DBF_{2}$ has been made utilizing the Green's function formalism. The force field for these molecules has been determined from the observed data. The eigenvector equations derived within the same formalism have been solved and the resulting normal coordinates will be presented. Agreement between observed and calculated frequencies was good. The observed fundamentals are presented in the following order $(cm^{-1}: H^{11}BF_{2}, D^{11}BF_{2}, D^{11}BF_{2}$, and $D^{10}BF_{2}: \nu_1$ (BF symmetric stretch), $1164, 1193, 1126, 1147; \nu_{2}$ (BH and BD stretch), $2621, 2621, 1960, 1960; \nu_{3}$ (BH symmetric deformation) $541.5,\ldots, 536,\l...
Author Institution: Department of Physics and Astronomy, University of TennesseeMeasurements of line...
The medium-resolution gas-phase infrared (IR) spectra of 1-bromo-1-fluoroethene (BrFC═CH2, 1,1-C2H2B...
$^{j}$. A. Philips, M Canagagar, H. Goodfriend, H. Grushow, J. Almlof and K.R Lepold J. Am. Chem. So...
Author Institution: North American Aviation Science CenterDibromoborane and dibromoborane-d have bee...
$^{1}$ M.C.L. Gerry. W. Lewis-Bevan, D.J. MacLennan, A.J. Merer, and N.P.C. Westwood, J. Mol. Spectr...
$^{*}$Supported by the Office of Ordoance Research, U. S. Army. $^{\dagger}$Now at Convair, Ft. Wort...
$^{1}$ J.M. Lisy, A. Tramer, M.F. Vernon and Y.T. Lee, J. Chem. Phys. 75, 4733 (1981). $^{2}$ A.S. P...
Calculations are presented of linewidths for the vibrational predissociation of D2 HF induced by exc...
In BF$_2$OH, difluoroboric acid, the OH group is the subject of a large amplitude torsion motion whi...
$^{1}$ K. Kawaguchi and E. Hirota, Chem. Phys. Letters 123, 1(1986). Adress: Fochbereich Chemie der ...
Author Institution: Department of Chemistery, Taxas Tech UniversityInfrared spectra are reported for...
A four dimensional (4D) time-dependent calculation to obtain the first vibrational states of the hyd...
$^{a}$H. -C. Chang and William Klemperer, J. Chem. Phys. 98, 2497(1993). $^{b}$R. M. Herman, R. H. T...
Author Institution: Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK; Dep...
$^{a}$ D.Collet, A.Perrin, H.B\""{u}rger, and J.-M.Flaud, J. Mol. Spectrosc. 212, 118 (2002)Author I...
Author Institution: Department of Physics and Astronomy, University of TennesseeMeasurements of line...
The medium-resolution gas-phase infrared (IR) spectra of 1-bromo-1-fluoroethene (BrFC═CH2, 1,1-C2H2B...
$^{j}$. A. Philips, M Canagagar, H. Goodfriend, H. Grushow, J. Almlof and K.R Lepold J. Am. Chem. So...
Author Institution: North American Aviation Science CenterDibromoborane and dibromoborane-d have bee...
$^{1}$ M.C.L. Gerry. W. Lewis-Bevan, D.J. MacLennan, A.J. Merer, and N.P.C. Westwood, J. Mol. Spectr...
$^{*}$Supported by the Office of Ordoance Research, U. S. Army. $^{\dagger}$Now at Convair, Ft. Wort...
$^{1}$ J.M. Lisy, A. Tramer, M.F. Vernon and Y.T. Lee, J. Chem. Phys. 75, 4733 (1981). $^{2}$ A.S. P...
Calculations are presented of linewidths for the vibrational predissociation of D2 HF induced by exc...
In BF$_2$OH, difluoroboric acid, the OH group is the subject of a large amplitude torsion motion whi...
$^{1}$ K. Kawaguchi and E. Hirota, Chem. Phys. Letters 123, 1(1986). Adress: Fochbereich Chemie der ...
Author Institution: Department of Chemistery, Taxas Tech UniversityInfrared spectra are reported for...
A four dimensional (4D) time-dependent calculation to obtain the first vibrational states of the hyd...
$^{a}$H. -C. Chang and William Klemperer, J. Chem. Phys. 98, 2497(1993). $^{b}$R. M. Herman, R. H. T...
Author Institution: Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK; Dep...
$^{a}$ D.Collet, A.Perrin, H.B\""{u}rger, and J.-M.Flaud, J. Mol. Spectrosc. 212, 118 (2002)Author I...
Author Institution: Department of Physics and Astronomy, University of TennesseeMeasurements of line...
The medium-resolution gas-phase infrared (IR) spectra of 1-bromo-1-fluoroethene (BrFC═CH2, 1,1-C2H2B...
$^{j}$. A. Philips, M Canagagar, H. Goodfriend, H. Grushow, J. Almlof and K.R Lepold J. Am. Chem. So...