Reactions of trichloro and tribromo complexes of ruthenium(III) and rhodium(III) with p-tolyl isocyanide

Srinivasamurthy, K.G.
Nanje Gowda, N.M.
Reddy, G.K.N.

Publication date

January 1979

Publisher

National Institute of Science Communication and Information Resources

Abstract

Trichloro and tribromo complexes of ruthenium and rhodium MX2(AsRPh2)3 (M = Ru, Rh; X = Cl, Br; R = Me, Et, Pr) react with p-tolyl isocyanide (p-tNC) in acetone or alc. to afford RuX2(AsRPh2)2(p-tNC)2 and RhX3(AsRPh2)2(p-tNC). The νCN values suggest an increase in the bond order of the CN group and decrease in π-character in the metal-C bond in the Rh complexes, and a decrease in the bond order of the CN group and an increase in the metal-C bond π-character in the Ru complexes

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Reactions of trichloro and tribromo complexes of ruthenium(III) and rhodium(III) with p-tolyl isocyanide

Abstract

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Reactions of trichloro and tribromo complexes of ruthenium(III) and rhodium(III) with p-tolyl isocyanide

Abstract

Extracted data

Related items

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Reactions of trichloro and tribromo complexes of ruthenium(III) and rhodium(III) with p-​tolyl isocyanide

Abstract

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Reactions of trichloro and tribromo complexes of ruthenium(III) and rhodium(III) with p-​tolyl isocyanide

Abstract

Extracted data

Related items

Related items

Reactions of trichloro and tribromo complexes of ruthenium(III) and rhodium(III) with p-tolyl isocyanide

Reactions of trichloro and tribromo complexes of ruthenium(III) and rhodium(III) with p-tolyl isocyanide