Reactions of a Ruthenium(VI) Nitride with Rhodium(III) and Iridium(III) Aryl Complexes. Insertion of the RuN Group into the Rh–C Bonds of Trimesitylrhodium(III)
- Enrique Kwan Huang (1753813)
- Wai-Man Cheung (1753819)
- Herman H. Y. Sung (1674736)
- Ian D. Williams (1642513)
- Wa-Hung Leung (1753816)
DOIAbstract
The reaction of the Ru<sup>VI</sup> nitride L<sub>OEt</sub>Ru<sup>VI</sup>(N)Cl<sub>2</sub> (<b>1</b>; L<sub>OEt</sub><sup>–</sup> = [Co(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>){P(O)(OEt)<sub>2</sub>}<sub>3</sub>]<sup>−</sup>) with Rh<sup>III</sup>(mes)<sub>3</sub> (mes = mesityl) results in insertion of the RuN group into the Rh–C bonds and formation of trinuclear (L<sub>OEt</sub>)ClRu<sup>IV</sup>(μ-Cl)(μ-2-CH<sub>2</sub>-4,6-Me<sub>2</sub>C<sub>6</sub>H<sub>2</sub>N)Rh<sup>III</sup>(μ-Nmes)(μ-Cl)<sub>2</sub>Ru<sup>IV</sup>(L<sub>OEt</sub>) (<b>2</b>), containing a cyclometalated μ-mesitylimido ligand, whereas that with Ir<sup>III</sup>(dtbpy)R<sub>3</sub> gives the μ-nitrido complexes (dtbpy)R<sub>3</sub>Ir<sup>III</sup>(μ-N...
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