Low temperature thermal to electrical energy converters have the potential to provide a route for recovering waste energy. In this paper, we propose a new configuration of a thermal harvester that uses a naturally driven thermal oscillator free of mechanical motion and operates between a hot heat source and a cold heat sink. The system exploits a heat induced liquid-vapour transition of a working fluid as a primary driver for a pyroelectric generator. The two-phase instability of a fluid in a closed looped capillary channel of an oscillating heat pipe (OHP) creates pressure differences which lead to local high frequency temperature oscillations in the range of 0.1–5 K. Such temperature changes are suitable for pyroelectric thermal to electr...