In this thesis optimal analytical controls derived using the framework of geometric control theory are used to plan motions for real engineering systems, and their performance assessed. Beginning with the nonholonomic wheeled robot on the 3-D Special Euclidean group, the co-ordinate free Maximum Principle of optimal control is used to create a kinematic motion planner via parametric optimisation. The reachable sets of the planner are investigated, and an obstacle avoidance framework is created and demonstrated. The practical applicability of this motion planner is assessed in both the unit speed and arbitrary speed cases. Subsequently, the natural motions of an axisymmetric and asymmetric rigid body are derived in convenient quaternion for...