We search for variations in the disk of Centaurus A of the emission from atomic fine structure lines using Herschel PACS and SPIRE spectroscopy. In particular, we observe the [C II](158 mu m), [N II](122 and 205 mu m), [O I](63 and 145 mu m), and [O III](88 mu m) lines, which all play an important role in cooling the gas in photo-ionized and photodissociation regions (PDRs). We determine that the ([C II]+[O I](63))/F-TIR line ratio, a proxy for the heating efficiency of the gas, shows no significant radial trend across the observed region, in contrast to observations of other nearby galaxies. We determine that 10%-20% of the observed [C II] emission originates in ionized gas. Comparison between our observations and a PDR model shows that th...