Orthopositronium (o-Ps) formation and decay can replace the annihilation process, when a positron interacts in liquid scintillator media. The delay induced by the positronium decay represents either a potential signature for antineutrino detection, via inverse β decay, or to identify and suppress positron background, as recently demonstrated by the Borexino experiment. The formation probability and decay time of o-Ps depend strongly on the surrounding material. In this paper, we characterize the o-Ps properties in liquid scintillators as function of concentrations of gadolinium, lithium, neodymium, and tellurium dopers used by present and future neutrino experiments. In particular, gadolinium and lithium are high neutron cross section isot...