A multistable molecular switching system based on an anthracene-extended bis-thiaxanthylidene with three individually addressable states that can be interconverted by electrochemical, thermal, and photochemical reactions is reported. Besides reversible switching between an open-shell diradical- and a closed-shell electronic configuration, our findings include a third dicationic state and control by multiple actuators. This dicationic state with an orthogonal conformation can be switched electrochemically with the neutral open-shell triplet state with orthogonal conformation, which was characterized by EPR. The remarkably stable diradical shows kinetic stability as a result of a significant activation barrier for isomerization to a more stab...
We report a novel class of star-shaped multiazobenzene photoswitches comprising individual photochro...
A family of heavy atom-free BODIPY?anthracene dyads (BADs) exhibiting triplet excited state formatio...
A subject of this work is group of organic compounds known as molecular switches. Molecular switches...
A multistable molecular switching system based on an anthracene-extended bis-thiaxanthylidene with t...
The ground- and the lowest singlet excited-state potential energy surfaces of the bis-thiaxanthylide...
This thesis focuses on organic electrochemical conversions with an emphasis on switches and biomass ...
In an approach toward a photochemically bistable molecular rotor the synthesis of cis-1a and trans-1...
Although bistability of molecular switches in solution is well established, achieving highly robust ...
In an approach toward a photochemically bistable molecular rotor the synthesis of cis-1a and trans-1...
Highly strained hydrocarbons with two di/tribenzocycloheptatriene units were designed as electrochro...
In an approach toward a photochemically bistable molecular rotor the synthesis of cis-1a and trans-1...
Nishiuchi T, Ito R, Stratmann E, Kubo T. Switchable Conformational Isomerization of an Overcrowded T...
Although the desirability of developing synthetic molecular machine systems that can function on sur...
Although the desirability of developing synthetic molecular machine systems that can function on sur...
We report a novel class of star-shaped multiazobenzene photoswitches comprising individual photochro...
A family of heavy atom-free BODIPY?anthracene dyads (BADs) exhibiting triplet excited state formatio...
A subject of this work is group of organic compounds known as molecular switches. Molecular switches...
A multistable molecular switching system based on an anthracene-extended bis-thiaxanthylidene with t...
The ground- and the lowest singlet excited-state potential energy surfaces of the bis-thiaxanthylide...
This thesis focuses on organic electrochemical conversions with an emphasis on switches and biomass ...
In an approach toward a photochemically bistable molecular rotor the synthesis of cis-1a and trans-1...
Although bistability of molecular switches in solution is well established, achieving highly robust ...
In an approach toward a photochemically bistable molecular rotor the synthesis of cis-1a and trans-1...
Highly strained hydrocarbons with two di/tribenzocycloheptatriene units were designed as electrochro...
In an approach toward a photochemically bistable molecular rotor the synthesis of cis-1a and trans-1...
Nishiuchi T, Ito R, Stratmann E, Kubo T. Switchable Conformational Isomerization of an Overcrowded T...
Although the desirability of developing synthetic molecular machine systems that can function on sur...
Although the desirability of developing synthetic molecular machine systems that can function on sur...
We report a novel class of star-shaped multiazobenzene photoswitches comprising individual photochro...
A family of heavy atom-free BODIPY?anthracene dyads (BADs) exhibiting triplet excited state formatio...
A subject of this work is group of organic compounds known as molecular switches. Molecular switches...