Heterogeneity of natural systems governs the pathway of pollutants in the environment, especially in aquifers. The relationship between a number of environmental pressures and the complex structure of groundwater flow systems generates many processes, which affect the behaviour and transport of pollutants. With regard to the wide variety of structural, volcanic and depositional processes which characterize the alluvial aquifer systems in the Campania Region (South Italy), this paper describes an integrated approach to delineate aquifer/aquitard units and recognize scale-dependent heterogeneity by means of geological, hydrogeological, geochemical and geostatistical techniques. In this analysis, a set of indicators, representative of the grou...