In this paper we deal with the problem of polarization diversity detection in compound-Gaussian clutter with unknown covariance matrix. To this end we assume that a set of secondary data, free of signal components and with the same covariance structure of the cell under test, is available. Due to the lack of a Uniformly Most Powerful (UMP) detector, we resort to a design procedure based upon the Rao test and the Wald test. Specifically, we first derive the Rao and the Wald tests assuming that the covariance matrix is known, then we plug into the derived decision rules a suitable estimate of the clutter covariance. Interestingly, the newly proposed detectors share the Constant False Alarm Rate (CFAR) property with respect to the texture stat...