Femtosecond pulsed laser deposition, carried out in high vacuum, leads the ablation of any target material, producing a plume of nano-drops which are deposited on a substrate as particles, preserving the parent material composition. The deposited nanoparticles (NPs) exhibit a characteristic disk-shape with a major diameter ranging from 5 nm up to 60 nm and a thickness ranging from 1 nm up to 10 nm. Also when the particles form a thick layer, they remain separated by an interface of free volume. This characteristic morphology of the deposited films gives an interplay of interparticle and intraparticle physical correlations which deeply differentiates their properties from those of similar nanogranular films deposited by other techniques. Thi...