We investigate the hierarchy of conic inner approximations Kn(r) (r∈N) for the copositive cone COPn, introduced by Parrilo (2000) [22]. It is known that COP4=K4(0) and that, while the union of the cones Kn(r) covers the interior of COPn, it does not cover the full cone COPn if n≥6. Here we investigate the remaining case n=5, where all extreme rays have been fully characterized by Hildebrand (2012) [12]. We show that the Horn matrix H and its positive diagonal scalings play an exceptional role among the extreme rays of COP5. We show that equality COP5=⋃r≥0K5(r) holds if and only if every positive diagonal scaling of H belongs to K5(r) for some r∈N. As a main ingredient for the proof, we introduce new Lasserre-type conic inner approximations ...