BICYCLO[3.3.1]NONANE APPROACH TO TRIQUINANES - FORMAL SYNTHESIS OF (+/-)-DELTA-9(12)CAPNELLENE AND (+/-)-DELTA-9(12)CAPNELLENE-8-BETA-10-ALPHA-DIOL

GAMBACORTA, Augusto
FABRIZI G
BOVICELLI P.

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Publication date

January 1992

DOI

10.1016/S0040-4020(01)80453-1

Publisher

Elsevier BV

Abstract

A new synthetic strategy for natural triquinanes is presented as a model study. Stereospecific rearrangement of the ready accessible bicyclo[3.3.1] nonanic acetoxychloride 6 gave the cis-pentalanic hydroxyaldehyde 5, which has been converted into the ketone 4 already reported as a key intermediate in some syntheses of the title capnellenes

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BICYCLO[3.3.1]NONANE APPROACH TO TRIQUINANES - FORMAL SYNTHESIS OF (+/-)-DELTA-9(12)CAPNELLENE AND (+/-)-DELTA-9(12)CAPNELLENE-8-BETA-10-ALPHA-DIOL

Abstract

Extracted data

BICYCLO[3.3.1]NONANE APPROACH TO TRIQUINANES - FORMAL SYNTHESIS OF (+/-)-DELTA-9(12)CAPNELLENE AND (+/-)-DELTA-9(12)CAPNELLENE-8-BETA-10-ALPHA-DIOL

Abstract

Extracted data

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