Rebar corrosion is one of the most important phenomena affecting durability of reinforced concrete structures. Corrosion inhibitors are considered an effective preventative technique to delay the onset of corrosion and/reduce the corrosion rare. Substances can be both organic and inorganic in nature. Besides the well-known effectiveness of nitrite-based inhibitor, new organic and inorganic substances have been investigated as alternative to face safety and environmental issues related to sodium or potassium nitrites. From the ‘90s, a wide number of organic substances were studied, including amines, alkanolamines, carboxylates and mixtures of esters. The present literature review is focused on the effectiveness of the most commonly used inhi...