10 pages, 4 figures, accepted for publication in Journal of Astrophysics and AstronomyAstrometric accuracy of complex modern VLBI arrays cannot be calculated analytically. We study the astrometric accuracy of phase-referenced VLBI observations for the VLBA, EVN and global VLBI array by simulating VLBI data for targets at declinations -25$^\circ$, 0$^\circ$, 25$^\circ$, 50$^\circ$, 75$^\circ$ and 85$^\circ$. The systematic error components considered in this study are calibrator position, station coordinate, Earth orientation and troposphere parameter uncertainties. We provide complete tables of the astrometric accuracies of these arrays for a source separation of 1$^\circ$ either along the right ascension axis or along the declination axis....