Add to ORKGSeveral racemic 1,2-diols bearing a tertiary benzylic alcohol stereogenic center can be esterified regioselectively by vinyl acetate using lipases and esterases in organic media. With the correct choice of enzyme and if the non-phenyl substituent at the tertiary center is unsaturated, E values of > 250 can be achieved.</p
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...
Several racemic 1,2-diols bearing a tertiary benzylic alcohol stereogenic center can be esterified r...
Several racemic 1,2-diols bearing a tertiary benzylic alcohol stereogenic center can be esterified r...
Several racemic 1,2-diols bearing a tertiary benzylic alcohol stereogenic center can be esterified r...
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...
Optically active 1,2-diols are valuable buildings blocks in organic synthesis. In the present paper,...
Optically active 1,2-diols are valuable buildings blocks in organic synthesis. In the present paper,...
The transesterification of 2-substituted-1,4-butanediols 1a, 2a and 3a with vinyl acetate catalyzed ...
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...
Several racemic 1,2-diols bearing a tertiary benzylic alcohol stereogenic center can be esterified r...
Several racemic 1,2-diols bearing a tertiary benzylic alcohol stereogenic center can be esterified r...
Several racemic 1,2-diols bearing a tertiary benzylic alcohol stereogenic center can be esterified r...
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...
Optically active 1,2-diols are valuable buildings blocks in organic synthesis. In the present paper,...
Optically active 1,2-diols are valuable buildings blocks in organic synthesis. In the present paper,...
The transesterification of 2-substituted-1,4-butanediols 1a, 2a and 3a with vinyl acetate catalyzed ...
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...
Diols 1, which contain adjacent tertiary and primary hydroxy groups, can be selectively mono-acylate...