The study considers the solution of a number of problems of supersonic and hypersonic gas dynamics using a model that takes into account the dissociation and ionization of air. The results of verification and validation of the developed numerical method using various difference schemes (the Roe scheme, Rusanov scheme, AUSM scheme) for discretizing convective flows are presented. The formulation of the mathematical model for high-temperature air uses the presence of equilibrium chemical reactions of dissociation and ionization. For this purpose, at high incoming flow velocities, the Kraiko model is applied, which includes equilibrium chemical reactions in air at high temperatures. To discretize the basic equations, the finite volume method...