© 2020 IEEE. Personal use of this material is permitted. Permission from IEEE must be obtained for all other uses, in any current or future media, including reprinting/republishing this material for advertising or promotional purposes, creating new collective works, for resale or redistribution to servers or lists, or reuse of any copyrighted component of this work in other works.[EN] The control of selective catalytic reduction (SCR) systems, via NH3 injection, requires from a precise estimation of the SCR load in order to ensure NOx reduction by minimizing ammonia slip. This article aims to resolve the cross-sensitivity of current NOx sensors at the outlet of the SCR, by providing the control unit with an estimation of NOx and ammonia sli...