The slow progress in the commercialization of lignocellulosic biorefineries involving the biochemical conversion pathway points at the immaturity of existing biorefinery concepts. The current research suggests a systematic analysis of value creation chains and their economic and environmental hotspots within a multi-product biorefinery, having as the primary goal to promote sustainable biorefining processes. A lignocellulosic biorefinery producing ethanol, crude lignin oil and electricity was analyzed. Our methodology involves the transformation of a technological biorefinery model into the input-output one and the use of matrix notation to track the accumulation of economic and environmental attributes along biorefinery value chains. Three...