[(IMes)2Pt(H)(ClBC5H4SiMe3)] : a Borabenzene–Platinum Adduct with an Unusual Pt‐Cl‐B Interaction
- Barnes, Stéphanie S.
- Bélanger-Chabot, Guillaume
- Languérand, André
- Maron, Laurent
- Berrouard, Philippe
- Audet, Pierre
Publication date
August 2009
DOI Publisher
Wiley Journal
Angewandte Chemie International Edition Language
EnglishAbstract
A Pt‐Cl‐B interaction is observed when a borabenzene derivative reacts with a platinum(0) precursor with bulky N‐heterocyclic carbene ligands. The resulting platinum(II) complex (see picture; Pt red, N blue, Cl green, B pink, Si yellow) involves a new bonding mode for borabenzene, which usually binds in an η6 fashion to transition metals
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