The reactivity of the manganese-benzyl complexes [(CO)5MnCH2C6H5-nXn] toward carbon monoxide insertion induced by tertiary phosphines in polar solvents has been studied. The steric influences of the alkyl group, solvent, and the phosphine are discussed
Cp'Mn(CO)3 (Cp'=h5-C5H4-CH 3) reacts with P(C6H5)2H in THF to give Cp'(CO)2MnPPh2H (Ph = Phenyl) (1)...
Reaction of [Mn(CO)5X] (X = Cl or Br) with L–L {L–L = dppm (Ph2PCH2PPh2), dppe (Ph2PCH2CH2PPh2), dpp...
The 31P NMR parameters ?(31P), nJ(31P31P), coordination shifts ?? and chelate-ring contributions ? a...
The rate constant, k3, for the direct insertion of carbon monoxide induced by tertiary phosphines in...
Infrared spectroscopy in the carbonyl stretching region and H NMR spectroscopy indicate that solvent...
The reactions of [(η5-C5Me5)(CO)3MoCH2Ph] and [(η5-C5H4Me)(CO)3MoCH2-Ph] with tertiary phosphines an...
The formation of phosphine-substituted acylmolybdenums [(η5-C5H5)-(CO)2(PPh3)Mo(COR)], from reaction...
The first order reactions of benzyl-molybdenum complexes, [(η5-C5H5)(CO)3Mo(CH2C6H4X)], with triphen...
The insertion reaction of carbon monoxide, induced by dimethylsulfoxide, into iron-carbon sigma bond...
Rate constants associated with the tertiary phosphine-induced formation of the metal acyls, [(η5-C5H...
The mechanism of reaction of alkyl isocyanides with [(η5-C5H5)(CO)3MoCH2C6H5] to yield isocyanide-su...
The aim of this study was to investigate the mechanism of phosphine induced migratory carbonyl inser...
The photochemistry of some d6 metal carbonyl complexes is investigated. In particular, the effect of...
Metal carbonyl complexes constitute a molecular family that is widely used in chemical processes sin...
Monomeric tetrahedral manganese dialkyl tertiary phosphine complexes of stoicheiometry MnR2 ( PR&apo...
Cp'Mn(CO)3 (Cp'=h5-C5H4-CH 3) reacts with P(C6H5)2H in THF to give Cp'(CO)2MnPPh2H (Ph = Phenyl) (1)...
Reaction of [Mn(CO)5X] (X = Cl or Br) with L–L {L–L = dppm (Ph2PCH2PPh2), dppe (Ph2PCH2CH2PPh2), dpp...
The 31P NMR parameters ?(31P), nJ(31P31P), coordination shifts ?? and chelate-ring contributions ? a...
The rate constant, k3, for the direct insertion of carbon monoxide induced by tertiary phosphines in...
Infrared spectroscopy in the carbonyl stretching region and H NMR spectroscopy indicate that solvent...
The reactions of [(η5-C5Me5)(CO)3MoCH2Ph] and [(η5-C5H4Me)(CO)3MoCH2-Ph] with tertiary phosphines an...
The formation of phosphine-substituted acylmolybdenums [(η5-C5H5)-(CO)2(PPh3)Mo(COR)], from reaction...
The first order reactions of benzyl-molybdenum complexes, [(η5-C5H5)(CO)3Mo(CH2C6H4X)], with triphen...
The insertion reaction of carbon monoxide, induced by dimethylsulfoxide, into iron-carbon sigma bond...
Rate constants associated with the tertiary phosphine-induced formation of the metal acyls, [(η5-C5H...
The mechanism of reaction of alkyl isocyanides with [(η5-C5H5)(CO)3MoCH2C6H5] to yield isocyanide-su...
The aim of this study was to investigate the mechanism of phosphine induced migratory carbonyl inser...
The photochemistry of some d6 metal carbonyl complexes is investigated. In particular, the effect of...
Metal carbonyl complexes constitute a molecular family that is widely used in chemical processes sin...
Monomeric tetrahedral manganese dialkyl tertiary phosphine complexes of stoicheiometry MnR2 ( PR&apo...
Cp'Mn(CO)3 (Cp'=h5-C5H4-CH 3) reacts with P(C6H5)2H in THF to give Cp'(CO)2MnPPh2H (Ph = Phenyl) (1)...
Reaction of [Mn(CO)5X] (X = Cl or Br) with L–L {L–L = dppm (Ph2PCH2PPh2), dppe (Ph2PCH2CH2PPh2), dpp...
The 31P NMR parameters ?(31P), nJ(31P31P), coordination shifts ?? and chelate-ring contributions ? a...
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