The aim of this study was to investigate the mechanism of phosphine induced migratory carbonyl insertion in the monocyclopentadienyliron(II) carbonyl complex, [η5- (C5H5)Fe(CO)2Me], upon variation of different parameters such as the type and the concentration of the phosphine ligand and the solvent. The mechanism that agrees with the results obtained is presented below.Prof. A. Rood
International audienceThe reaction of substitution of carbon monoxide by P(OMe)3 in the complex (μ-η...
The reactivity of the manganese-benzyl complexes [(CO)5MnCH2C6H5-nXn] toward carbon monoxide inserti...
Fluorophosphinidene (PF) is a versatile ligand found experimentally in the transient species M(CO)<...
The reactions of the complexes [Fe(eta(5)-L)(CO)(2)R] (L = C5H5 or C9H7, R = Me or CHMe(2)) with PR'...
The indenyl complex (eta5-C9H7)Fe(CO)2Me reacts with phosphines (PMe3, PMe2Ph, PMePh2, PPh3) in tolu...
The reaction of indenyl complexes (CgH7)Fe(CO)zR (R = CHMez, Me) with phosphines in toluene (20-60 "...
Reaction between solid (C5H5)Fe(CO) 2CH3 and a range of solid phosphine ligands, L (L = PPh3, P(m-CH...
The compound [Fe(eta-C5H5)(CO)2(Me)] reacts thermally with N-heterocyclic carbenes (L) to give both ...
The iron complexes [Fe(eta(5)-ligand)(CO)(2)R][ligand = C5H5 (Cp), R = Me (1); ligand = C5H5, R = CH...
We have found that {eta}{sup 5}-methylcyclopentadienyl- (triphenylphosphine)dimethylcobalt(III) (1) ...
The structures in solution and the electronic effects induced by the ligands L in the series (benzyl...
The reactivity of the σ,π-thienyl complex [Fe2(CO)6(μ-Th)(μ-PTh2)] (1) towards a range of phosphines...
The rate constant, k3, for the direct insertion of carbon monoxide induced by tertiary phosphines in...
International audienceReaction of the base-containing diphosphine (Ph2PCH2)2NCH3 with [Fe2(CO)6(μ-S2...
The mechanism of phosphine- and phosphite-induced migration of the imido group from sulfur to a Cp r...
International audienceThe reaction of substitution of carbon monoxide by P(OMe)3 in the complex (μ-η...
The reactivity of the manganese-benzyl complexes [(CO)5MnCH2C6H5-nXn] toward carbon monoxide inserti...
Fluorophosphinidene (PF) is a versatile ligand found experimentally in the transient species M(CO)<...
The reactions of the complexes [Fe(eta(5)-L)(CO)(2)R] (L = C5H5 or C9H7, R = Me or CHMe(2)) with PR'...
The indenyl complex (eta5-C9H7)Fe(CO)2Me reacts with phosphines (PMe3, PMe2Ph, PMePh2, PPh3) in tolu...
The reaction of indenyl complexes (CgH7)Fe(CO)zR (R = CHMez, Me) with phosphines in toluene (20-60 "...
Reaction between solid (C5H5)Fe(CO) 2CH3 and a range of solid phosphine ligands, L (L = PPh3, P(m-CH...
The compound [Fe(eta-C5H5)(CO)2(Me)] reacts thermally with N-heterocyclic carbenes (L) to give both ...
The iron complexes [Fe(eta(5)-ligand)(CO)(2)R][ligand = C5H5 (Cp), R = Me (1); ligand = C5H5, R = CH...
We have found that {eta}{sup 5}-methylcyclopentadienyl- (triphenylphosphine)dimethylcobalt(III) (1) ...
The structures in solution and the electronic effects induced by the ligands L in the series (benzyl...
The reactivity of the σ,π-thienyl complex [Fe2(CO)6(μ-Th)(μ-PTh2)] (1) towards a range of phosphines...
The rate constant, k3, for the direct insertion of carbon monoxide induced by tertiary phosphines in...
International audienceReaction of the base-containing diphosphine (Ph2PCH2)2NCH3 with [Fe2(CO)6(μ-S2...
The mechanism of phosphine- and phosphite-induced migration of the imido group from sulfur to a Cp r...
International audienceThe reaction of substitution of carbon monoxide by P(OMe)3 in the complex (μ-η...
The reactivity of the manganese-benzyl complexes [(CO)5MnCH2C6H5-nXn] toward carbon monoxide inserti...
Fluorophosphinidene (PF) is a versatile ligand found experimentally in the transient species M(CO)<...
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