This thesis is concerned with the properties of insulating crystals. At first glance, it might not seem very interesting to study the electronic properties of such materials, as there is no conduction possible. Why then would one devote an entire thesis to this topic? The answer is that there exists a class of peculiar insulators, which are insulating in the interior of the material, but conducting at the edges. We mostly consider crystalline (topological) insulators, and more specifically insulators possessing a rotational symmetry. The atoms of such a material form a lattice that is two-, three-, four- or six-fold rotational symmetric. If this symmetry is broken, any conductive edge states present disappear. Apart from conduction edge...