Intramolecular rearrangement of the imine-amide ligand within the nickel coordination sphere affected by carbon monoxide

The interactions of the nickel imine-amide allyl complex [D-2-C=N (N) over cap Ni)CNi(eta(3)-allyl)] 1 with carbon monoxide and unsaturated hydrocarbons have been studied. It is shown that this complex reacts readily with carbon monoxide to form the nickel(0) diimine carbonyl complex [(2-(1-propenyl)-[1,10] phenanthroline) Ni(CO)(2)](2). During the process the ligand undergoes a deep transformation within the nickel coordination sphere. Specifically, the nickel-nitrogen sigma-bond turns to an N-donor bond with aromatization of a ring in the nitrogen-containing ligand. This novel heteroaromatic ligand 2-(1-propenyl)-[1,10] phenanthroline has been isolated; the nickel(0) diimine carbonyl complex 2 has been studied with X-ray diffraction method. The comparative spectral studies of complexes 1, 2, and 2-(1-propenyl)-[1,10] phenanthroline have been carried out with UV/vis, IR-FT, and 2D NMR spectroscopy. It has been shown that the planar 16-electron nickel(II) imine-amide allyl complex 1 is indifferent to olefins and acetylenes. Based on the NMR data, this fact can be explained by the inability of the pi-delta rearrangement into 1. (C) 2011 Elsevier B. V. All rights reserved