In this study, we describe reaction chemistry of the first nickel(II) complexes having a terminally bound imido ligand, (dtbpe)Ni=NR (R = 2,6-ⁱPr₂C₆H₃, 2,3,6-Me₃C₆H₂ (Mes), and Ad) with various small unsaturated molecules
The reaction of ammonium and iminium tetraphenylborate salts ((CH2CHCH2NH3)BPh4, [(CH2CHCH2)HNCMe2]B...
Three distinct oxidation states of a nickel carbonyl species, formally Ni(II), +1 and 0, (compounds ...
The first part of this thesis deals with a mechanistic investigation into the conversion of the know...
The three-coordinate imidos (dtbpe)NiNR (dtbpe = <sup><i>t</i></sup>Bu<sub>2</sub>PCH<sub>2</sub>C...
This thesis examines the use of hemi-labile amidate and ureate ligands on nickel metal centers in th...
(Chemical Equation Presented) Bis(imino)pyridine complex [Ni{2,6-(ArN=CMe)2C5H3N}Cl] (where Ar = 2,6...
The bis-[β-carbonylenolato)nickel(II) complexes [Ni(eaa) 2] (eaa = ethylacetoacetato), [Ni(ba) 2] (b...
Ligands that can adapt their coordination mode to the electronic properties of a metal center are of...
Imido complexes are a class of organometallic compounds composed of a metal bonded with a divalent n...
The interactions of the nickel imine-amide allyl complex [D-2-C=N (N) over cap Ni)CNi(eta(3)-allyl)]...
Three novel Ni complexes with the Schiff base ligand 2-methoxy-6-(E-2-pyridyliminomethyl)-phenol (L1...
The coordination chemistry of a series of diphosphine-imine ligands (PCNP) to Ni is investigated, wi...
Reaction of L<sup>0</sup>NiBr<sub>2</sub> with 2 equiv of NaH yielded the Ni<sup>II</sup> hydride co...
After the lithiation of PYRH2 (PYR2− =[{NC(Me)C(H)C(Me)NC6H3(iPr)2}2(C5H3N)]2−), which is the precur...
After the lithiation of PYRH2 (PYR2− =[{NC(Me)C(H)C(Me)NC6H3(iPr)2}2(C5H3N)]2−), which is the precur...
The reaction of ammonium and iminium tetraphenylborate salts ((CH2CHCH2NH3)BPh4, [(CH2CHCH2)HNCMe2]B...
Three distinct oxidation states of a nickel carbonyl species, formally Ni(II), +1 and 0, (compounds ...
The first part of this thesis deals with a mechanistic investigation into the conversion of the know...
The three-coordinate imidos (dtbpe)NiNR (dtbpe = <sup><i>t</i></sup>Bu<sub>2</sub>PCH<sub>2</sub>C...
This thesis examines the use of hemi-labile amidate and ureate ligands on nickel metal centers in th...
(Chemical Equation Presented) Bis(imino)pyridine complex [Ni{2,6-(ArN=CMe)2C5H3N}Cl] (where Ar = 2,6...
The bis-[β-carbonylenolato)nickel(II) complexes [Ni(eaa) 2] (eaa = ethylacetoacetato), [Ni(ba) 2] (b...
Ligands that can adapt their coordination mode to the electronic properties of a metal center are of...
Imido complexes are a class of organometallic compounds composed of a metal bonded with a divalent n...
The interactions of the nickel imine-amide allyl complex [D-2-C=N (N) over cap Ni)CNi(eta(3)-allyl)]...
Three novel Ni complexes with the Schiff base ligand 2-methoxy-6-(E-2-pyridyliminomethyl)-phenol (L1...
The coordination chemistry of a series of diphosphine-imine ligands (PCNP) to Ni is investigated, wi...
Reaction of L<sup>0</sup>NiBr<sub>2</sub> with 2 equiv of NaH yielded the Ni<sup>II</sup> hydride co...
After the lithiation of PYRH2 (PYR2− =[{NC(Me)C(H)C(Me)NC6H3(iPr)2}2(C5H3N)]2−), which is the precur...
After the lithiation of PYRH2 (PYR2− =[{NC(Me)C(H)C(Me)NC6H3(iPr)2}2(C5H3N)]2−), which is the precur...
The reaction of ammonium and iminium tetraphenylborate salts ((CH2CHCH2NH3)BPh4, [(CH2CHCH2)HNCMe2]B...
Three distinct oxidation states of a nickel carbonyl species, formally Ni(II), +1 and 0, (compounds ...
The first part of this thesis deals with a mechanistic investigation into the conversion of the know...
DOI
Add to ORKG