The Cope rearrangement of gem-dimethyl-substituted divinylcyclopropanes has been used to construct functionalised cycloheptadienes. These scaffolds have been further elaborated to furnish advanced intermediates en route to africanane sesquiterpene natural products, most notably pyxidatol C
The use of ring-fused gem-dihalocyclopropanes, Au(I)-catalyzed cyclization reactions, and chemoenzym...
Part I: The synthesis of (+/-) cuparene and (+/-) cuparenic acid was achieved starting from 3-methyl...
The work described in this thesis has been divided into three parts: Chapter One describes several u...
The Cope rearrangement of gem-dimethyl-substituted divinylcyclopropanes has been used to construct f...
Studies towards the total synthesis of pyxidatol C I, isolated from the medicinal mushroom Clavico...
A diastereoselective route to the 5,7,5-tricyclic core of the guianolides is presented. This route r...
This thesis explores the development of the tandem oxy-Cope/ene rearrangement and its application to...
An advanced intermediate in a route to the odoriferous sesquiterpenoid grimaldone has been synthesis...
Addition of alkenyl Grignard reagents to (1-methoxycarbonylpentadienyl)iron(1+) cation generates the...
An attempt to synthesize the cyclohexane core of antibiotic abyssomicin C is described. The initial,...
The development of efficient strategies for the synthesis of complex organic molecular architectures...
Natural product total synthesis provides an alternative method for obtaining medicinally relevant co...
Progress has been made towards the synthesis of the odoriferous tricyclic sesquiterpenoid grimaldone...
A modular synthetic platform for the synthesis of the multi-bioactive sesquiterpene-tropolone natura...
Trans-cyclobutane-containing meroterpenoids are a structurally intriguing class of natural products ...
The use of ring-fused gem-dihalocyclopropanes, Au(I)-catalyzed cyclization reactions, and chemoenzym...
Part I: The synthesis of (+/-) cuparene and (+/-) cuparenic acid was achieved starting from 3-methyl...
The work described in this thesis has been divided into three parts: Chapter One describes several u...
The Cope rearrangement of gem-dimethyl-substituted divinylcyclopropanes has been used to construct f...
Studies towards the total synthesis of pyxidatol C I, isolated from the medicinal mushroom Clavico...
A diastereoselective route to the 5,7,5-tricyclic core of the guianolides is presented. This route r...
This thesis explores the development of the tandem oxy-Cope/ene rearrangement and its application to...
An advanced intermediate in a route to the odoriferous sesquiterpenoid grimaldone has been synthesis...
Addition of alkenyl Grignard reagents to (1-methoxycarbonylpentadienyl)iron(1+) cation generates the...
An attempt to synthesize the cyclohexane core of antibiotic abyssomicin C is described. The initial,...
The development of efficient strategies for the synthesis of complex organic molecular architectures...
Natural product total synthesis provides an alternative method for obtaining medicinally relevant co...
Progress has been made towards the synthesis of the odoriferous tricyclic sesquiterpenoid grimaldone...
A modular synthetic platform for the synthesis of the multi-bioactive sesquiterpene-tropolone natura...
Trans-cyclobutane-containing meroterpenoids are a structurally intriguing class of natural products ...
The use of ring-fused gem-dihalocyclopropanes, Au(I)-catalyzed cyclization reactions, and chemoenzym...
Part I: The synthesis of (+/-) cuparene and (+/-) cuparenic acid was achieved starting from 3-methyl...
The work described in this thesis has been divided into three parts: Chapter One describes several u...
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