A palladium-catalyzed (3 + 2) cycloaddition of a vinylcyclopropane and a β-nitrostyrene is employed to rapidly assemble the cyclopentane core of the Melodinus alkaloids. The ABCD ring system of the natural product family is prepared in six steps from commercially available materials
This manuscript presents the development of novel palladium-catalysed [3+2] cycloaddition reactions ...
Studies towards the development of a novel methodology have been achieved. A Palladium-catalysed [3 ...
A straightforward total synthesis of the cyclooctenoid sesquiterpene dactylol (1) and of 3a-epi-dact...
A series of highly substituted vinylcyclopropanes were prepared and examined as reaction partners in...
Donor–acceptor cyclopropanes are a versatile class of synthetic intermediates, compatible in a broad...
The Stemona alkaloids are a structurally interesting class of alkaloids isolated from the roots and ...
A tandem anionic 5-exo-dig cyclization/Claisen rearrangement sequence was used to effect a facile, “...
General catalytic asymmetric routes toward cyclopentanoid and cycloheptanoid core structures embedde...
AbstractReaction of 2,2-dimethyl-1,3-dioxane-4,6-dione (Meldrum’s acid) with various aldehydes in th...
A stereospecific palladium-catalyzed N-vinylation of azaheterocycles with vinyl triflates is describ...
The tetracyclic core of the integrastatin natural products has been prepared in a convergent and ra...
We report our iterative efforts toward the divergent total syntheses of curcusones A–D via Suzuki co...
A set of mild processes for the conversion of vinyl cyclopropyl diazo ketones to highly functionaliz...
Contraction action! A simple protocol for the catalytic asymmetric synthesis of highly functionalize...
Open sesame: A direct synthesis of functionalised and stereodefined dienes, relying on a domino ally...
This manuscript presents the development of novel palladium-catalysed [3+2] cycloaddition reactions ...
Studies towards the development of a novel methodology have been achieved. A Palladium-catalysed [3 ...
A straightforward total synthesis of the cyclooctenoid sesquiterpene dactylol (1) and of 3a-epi-dact...
A series of highly substituted vinylcyclopropanes were prepared and examined as reaction partners in...
Donor–acceptor cyclopropanes are a versatile class of synthetic intermediates, compatible in a broad...
The Stemona alkaloids are a structurally interesting class of alkaloids isolated from the roots and ...
A tandem anionic 5-exo-dig cyclization/Claisen rearrangement sequence was used to effect a facile, “...
General catalytic asymmetric routes toward cyclopentanoid and cycloheptanoid core structures embedde...
AbstractReaction of 2,2-dimethyl-1,3-dioxane-4,6-dione (Meldrum’s acid) with various aldehydes in th...
A stereospecific palladium-catalyzed N-vinylation of azaheterocycles with vinyl triflates is describ...
The tetracyclic core of the integrastatin natural products has been prepared in a convergent and ra...
We report our iterative efforts toward the divergent total syntheses of curcusones A–D via Suzuki co...
A set of mild processes for the conversion of vinyl cyclopropyl diazo ketones to highly functionaliz...
Contraction action! A simple protocol for the catalytic asymmetric synthesis of highly functionalize...
Open sesame: A direct synthesis of functionalised and stereodefined dienes, relying on a domino ally...
This manuscript presents the development of novel palladium-catalysed [3+2] cycloaddition reactions ...
Studies towards the development of a novel methodology have been achieved. A Palladium-catalysed [3 ...
A straightforward total synthesis of the cyclooctenoid sesquiterpene dactylol (1) and of 3a-epi-dact...