(Aryl aldehyde)- and (aryl ketone)-chromium tricarbonyl complexes ortho-substituted with the chiral auxiliary O-methyl-N-(α-methylbenzyl)hydroxylamine undergo diastereoselective addition of Grignard reagents and Super-Hydride®, respectively, to give the corresponding secondary alcohols in high diastereoisomeric purity. These compounds may be easily decomplexed and deprotected to give the corresponding enantiopure amino alcohols
Treatment of acetals derived from ortho substituted benzaldehyde chromium tricarbonyl complexes and ...
Addition of organolithium or Grignard reagents to ( R)- or (S)-O-(1-phenylbutyl)aldehyde oximes 1 in...
Asymmetric syntheses of (+)-(αR)-benzaldehyde and (+)-(αR)-o-anisaldehyde methyl isopropyl acetals i...
(Aryl aldehyde)- and (aryl ketone)-chromium tricarbonyl complexes ortho-substituted with the chiral ...
ABSTRACT: The use of O-methyl-N-(alpha-methylbenzyl)hydroxylamine as a novel chiral auxiliary in asy...
The use of the (S)-α-methylbenzyl group as a chiral auxiliary has allowed the diastereoselective ort...
The γ-amino alcohol structural motif is often encountered in drugs and natural products. We develope...
The title reagents cleave diastereoselectively the acetals derived from various aldehydes and chiral...
The use of O-methyl-N-(α-methylbenzyl)hydroxylamine as a novel chiral auxiliary in asymmetric ortho-...
The diastereoselective conjugate addition of lithium (R)-N-benzyl-N-α-methylbenzylamide to α,β-unsat...
Remarkable progress in the enantioselective addition of Grignard reagents to carbonyl compounds has ...
Asymmetric synthesis has emerged as one of the most rap-idly developing research areas in organic ch...
Remarkable progress in the enantioselective addition of Grignard reagents to carbonyl compounds has ...
The asymmetric synthesis of cis-1,4-amino alcohols with a norbornene backbone was performed starting...
A summary of the work on asymmetric reduction of carbonyl compounds with chiral alkoxyaluminium and ...
Treatment of acetals derived from ortho substituted benzaldehyde chromium tricarbonyl complexes and ...
Addition of organolithium or Grignard reagents to ( R)- or (S)-O-(1-phenylbutyl)aldehyde oximes 1 in...
Asymmetric syntheses of (+)-(αR)-benzaldehyde and (+)-(αR)-o-anisaldehyde methyl isopropyl acetals i...
(Aryl aldehyde)- and (aryl ketone)-chromium tricarbonyl complexes ortho-substituted with the chiral ...
ABSTRACT: The use of O-methyl-N-(alpha-methylbenzyl)hydroxylamine as a novel chiral auxiliary in asy...
The use of the (S)-α-methylbenzyl group as a chiral auxiliary has allowed the diastereoselective ort...
The γ-amino alcohol structural motif is often encountered in drugs and natural products. We develope...
The title reagents cleave diastereoselectively the acetals derived from various aldehydes and chiral...
The use of O-methyl-N-(α-methylbenzyl)hydroxylamine as a novel chiral auxiliary in asymmetric ortho-...
The diastereoselective conjugate addition of lithium (R)-N-benzyl-N-α-methylbenzylamide to α,β-unsat...
Remarkable progress in the enantioselective addition of Grignard reagents to carbonyl compounds has ...
Asymmetric synthesis has emerged as one of the most rap-idly developing research areas in organic ch...
Remarkable progress in the enantioselective addition of Grignard reagents to carbonyl compounds has ...
The asymmetric synthesis of cis-1,4-amino alcohols with a norbornene backbone was performed starting...
A summary of the work on asymmetric reduction of carbonyl compounds with chiral alkoxyaluminium and ...
Treatment of acetals derived from ortho substituted benzaldehyde chromium tricarbonyl complexes and ...
Addition of organolithium or Grignard reagents to ( R)- or (S)-O-(1-phenylbutyl)aldehyde oximes 1 in...
Asymmetric syntheses of (+)-(αR)-benzaldehyde and (+)-(αR)-o-anisaldehyde methyl isopropyl acetals i...