One of the greatest challenges of modern theoretical physics is to find a quantum theory of gravity that could unify general relativity and quantum mechanics. The microscopic understanding of black holes plays an essential role in pursuing this goal for its unique connection between gravity and quantum effects. Despite the remarkable progress that has been made towards this direction, most developments rely heavily on supersymmetry and elude more realistic non-supersymmetric (nonBPS) black holes. This thesis is to improve this situation and develop both the macroscopic and microscopic sides of nonBPS black holes. In the first part of this thesis, we study a special class of nonBPS black hole solutions in supergravity theories and comput...