Add to ORKGAtropisomers possessing multiple stereogenic axes are intriguing molecules with huge potential. However, only few approaches for their enantioselective synthesis are available due to the difficulties in assembling various stereogenic axes with high enantiocontrol. Only recently, innovative methods have emerged, opening new possibilities for the synthesis of this original class of atropisomeric compounds. This Minireview describes the development of this field based on a classification of the multi-axis systems according to the distance between the stereogenic axes and the strategy used to build them
Owing to their favorable molecular topology, atropisomers represent particularly valuable chiral sca...
This thesis describes the development of novel methods to synthesise non-biaryl atropisomers enantio...
The synthetic equivalents of the enantiopure binaphthyl bis(aryne) atropisomers derived from BINOL (...
Atropisomers possessing multiple stereogenic axes are intriguing molecules with huge potential. Howe...
A strategy to prepare compounds with multiple chirality axes, which has led to a concise total synth...
International audienceAtropisomerism is a fundamental property of molecules featuring a hindered rot...
Perhaps the most well-recognized stereogenic elements within chiral molecules are sp3-hybridized car...
Atroposelective addition of axially chiral laterally lithiated 2-alkyl- 1-naphthamides to 6-substitu...
Addition of laterally lithiated tertiary aromatic amides to benzaldimines controls the formation of ...
Molecular scaffolds with multiple rotationally restricted bonds allow a precise spatial positioning ...
Nonbiaryl atropisomers are molecules defined by a stereogenic axis featuring at least one nonarene m...
One of the most well-recognized stereogenic elements in a chiral molecule is an sp(3)-hybridized car...
Atropisomerism represents a form of chirality that is often swept under the rug in medicinal chemist...
The enantioselective synthesis of atropisomers is an emerging field, that in recent yearsreached fun...
Owing to their favorable molecular topology, atropisomers represent particularly valuable chiral sca...
This thesis describes the development of novel methods to synthesise non-biaryl atropisomers enantio...
The synthetic equivalents of the enantiopure binaphthyl bis(aryne) atropisomers derived from BINOL (...
Atropisomers possessing multiple stereogenic axes are intriguing molecules with huge potential. Howe...
A strategy to prepare compounds with multiple chirality axes, which has led to a concise total synth...
International audienceAtropisomerism is a fundamental property of molecules featuring a hindered rot...
Perhaps the most well-recognized stereogenic elements within chiral molecules are sp3-hybridized car...
Atroposelective addition of axially chiral laterally lithiated 2-alkyl- 1-naphthamides to 6-substitu...
Addition of laterally lithiated tertiary aromatic amides to benzaldimines controls the formation of ...
Molecular scaffolds with multiple rotationally restricted bonds allow a precise spatial positioning ...
Nonbiaryl atropisomers are molecules defined by a stereogenic axis featuring at least one nonarene m...
One of the most well-recognized stereogenic elements in a chiral molecule is an sp(3)-hybridized car...
Atropisomerism represents a form of chirality that is often swept under the rug in medicinal chemist...
The enantioselective synthesis of atropisomers is an emerging field, that in recent yearsreached fun...
Owing to their favorable molecular topology, atropisomers represent particularly valuable chiral sca...
This thesis describes the development of novel methods to synthesise non-biaryl atropisomers enantio...
The synthetic equivalents of the enantiopure binaphthyl bis(aryne) atropisomers derived from BINOL (...