Add to ORKGStructural parameters of free and metal coordinated sulfoxides are reviewed and updated average values are derived. For uncoordinated sulfoxides, the average S−O bond distance is 1.4918(9) Å. This value is lengthened to 1.528(1) Å upon O-coordination to metal ions, while it is reduced to 1.4731(6) Å upon S-coordination. The sulfoxide bonding and bridging modes are discussed together with some stereochemical features
Density functional (DFT) calculations at M05-2x/aug-cc-pVDZ level were used to analyze the interacti...
The reaction of H2[OsBr6] with DMSO in ethanol solution resulted in DMSO complex [H(dmso-O)2][OsIII(...
Complex [H(dmso)]2[OsIVCl6] ⋅ 2H2O (1) was synthesized by refluxing of [H(dmso)2]2[OsCl6] in concent...
The title compound, C 2 H 6 OS, is a high melting, polar and aprotic solvent widely used in org...
The synthesis of the new ligand bis(6-diphenylphosphinoacenaphth-5-yl)sulfoxide, [6-(Ph2P)-5-Ace-6](...
It is hard to talk about dimethyl sulfoxide (DMSO) without sounding like an old-time carnival snake-...
We have structurally characterized and investigated a range of sulfoxide compounds containing aryl a...
Redox-stimulated intramolecular isomerization of the DMSO ligand in [Os(bpy)<sub>2</sub>(DMSO)<sub>...
Areas of hypoxia (low O₂ content) within malignant tumours are often resistant to radiotherapy and c...
Dimethyl sulphoxide (DMSO) molecules in their all-organic solvates were shown to interact with arene...
The discovery that halo−ruthenium(sulfoxide) complexes exhibit anticancer activity has stimulated in...
Density functional (DFT) calculations at M05-2x/aug-cc-pVDZ level were used to analyze the interacti...
Complex [H(dmso)]2[OsIVCl6] ⋅ 2H2O (1) was synthesized by refluxing of [H(dmso)2]2[OsCl6] in concent...
A computational study of the stability and the cooperative effect of hydrogen bonds in the complexes...
The literature data on the synthesis, stoichiometry, structure and relative stability of molecular ...
Density functional (DFT) calculations at M05-2x/aug-cc-pVDZ level were used to analyze the interacti...
The reaction of H2[OsBr6] with DMSO in ethanol solution resulted in DMSO complex [H(dmso-O)2][OsIII(...
Complex [H(dmso)]2[OsIVCl6] ⋅ 2H2O (1) was synthesized by refluxing of [H(dmso)2]2[OsCl6] in concent...
The title compound, C 2 H 6 OS, is a high melting, polar and aprotic solvent widely used in org...
The synthesis of the new ligand bis(6-diphenylphosphinoacenaphth-5-yl)sulfoxide, [6-(Ph2P)-5-Ace-6](...
It is hard to talk about dimethyl sulfoxide (DMSO) without sounding like an old-time carnival snake-...
We have structurally characterized and investigated a range of sulfoxide compounds containing aryl a...
Redox-stimulated intramolecular isomerization of the DMSO ligand in [Os(bpy)<sub>2</sub>(DMSO)<sub>...
Areas of hypoxia (low O₂ content) within malignant tumours are often resistant to radiotherapy and c...
Dimethyl sulphoxide (DMSO) molecules in their all-organic solvates were shown to interact with arene...
The discovery that halo−ruthenium(sulfoxide) complexes exhibit anticancer activity has stimulated in...
Density functional (DFT) calculations at M05-2x/aug-cc-pVDZ level were used to analyze the interacti...
Complex [H(dmso)]2[OsIVCl6] ⋅ 2H2O (1) was synthesized by refluxing of [H(dmso)2]2[OsCl6] in concent...
A computational study of the stability and the cooperative effect of hydrogen bonds in the complexes...
The literature data on the synthesis, stoichiometry, structure and relative stability of molecular ...
Density functional (DFT) calculations at M05-2x/aug-cc-pVDZ level were used to analyze the interacti...
The reaction of H2[OsBr6] with DMSO in ethanol solution resulted in DMSO complex [H(dmso-O)2][OsIII(...
Complex [H(dmso)]2[OsIVCl6] ⋅ 2H2O (1) was synthesized by refluxing of [H(dmso)2]2[OsCl6] in concent...