Add to ORKGComplex [H(dmso)]2[OsIVCl6] ⋅ 2H2O (1) was synthesized by refluxing of [H(dmso)2]2[OsCl6] in concentrated HCl and characterized by the IR and UV/Vis spectroscopy and X-ray powder and single-crystal diffraction studies. In this complex, rare highly electrophilic [Me2S=O⋅⋅⋅H]+ cation is stabilized by multiple chalcogen bonds including bifurcated S⋅⋅⋅(Cl)3 and S⋅⋅⋅Cl non-covalent interactions. DFT calculations and topological analysis of the electron density distribution within the formalism of Bader's theory (QTAIM method) support the presence of intermolecular non-covalent interactions S⋅⋅⋅Cl and O⋅⋅⋅Cl in the solid state
The highly unusual Mo(VI) thioether complexes [MoO2X2(L-L)] (X = Cl or Br; L-L = MeS(CH2)(2)SMe or E...
By using accurate density functional theory calculations, we have studied the cluster complexes of a...
The title compound was prepared by base hydrolysis of (p-MeOC6H4)2SeCl2 in water and isolated as the...
Complex [H(dmso)]2[OsIVCl6] ⋅ 2H2O (1) was synthesized by refluxing of [H(dmso)2]2[OsCl6] in concent...
Two osmium complexes of common formula [H(dmso)2][OsIVХ5(dmso-κO)] 1 (Х=Cl) and 2 (Х=Br) are synthes...
The reactions of H2OsX6 · nH2O (X = Cl, Br) with dimethyl sulfoxide (DMSO) or DMSO-d6 in acetone aff...
The reaction of H2[OsBr6] with DMSO in ethanol solution resulted in DMSO complex [H(dmso-O)2][OsIII(...
X-ray diffraction is used to study complex [H(DMSO)2][OsBr4(DMSO)2] (1). The compound crystallizes i...
Density functional (DFT) calculations at M05-2x/aug-cc-pVDZ level were used to analyze the interacti...
Density functional (DFT) calculations at M05-2x/aug-cc-pVDZ level were used to analyze the interacti...
Bromo dimethyl sulfoxide osmium(II) complexes were synthesized: trans-[OsBr2(dmso-S)4] (1) was obtai...
Structural parameters of free and metal coordinated sulfoxides are reviewed and updated average valu...
The title compound, C 2 H 6 OS, is a high melting, polar and aprotic solvent widely used in org...
Osmium is the most rare and scattered element of platinum group metals. Dimethyl sulfoxide complexes...
The reactions between MoCl5and 1–2 equiv. of a selection of sulfoxides at room temperature in dichlo...
The highly unusual Mo(VI) thioether complexes [MoO2X2(L-L)] (X = Cl or Br; L-L = MeS(CH2)(2)SMe or E...
By using accurate density functional theory calculations, we have studied the cluster complexes of a...
The title compound was prepared by base hydrolysis of (p-MeOC6H4)2SeCl2 in water and isolated as the...
Complex [H(dmso)]2[OsIVCl6] ⋅ 2H2O (1) was synthesized by refluxing of [H(dmso)2]2[OsCl6] in concent...
Two osmium complexes of common formula [H(dmso)2][OsIVХ5(dmso-κO)] 1 (Х=Cl) and 2 (Х=Br) are synthes...
The reactions of H2OsX6 · nH2O (X = Cl, Br) with dimethyl sulfoxide (DMSO) or DMSO-d6 in acetone aff...
The reaction of H2[OsBr6] with DMSO in ethanol solution resulted in DMSO complex [H(dmso-O)2][OsIII(...
X-ray diffraction is used to study complex [H(DMSO)2][OsBr4(DMSO)2] (1). The compound crystallizes i...
Density functional (DFT) calculations at M05-2x/aug-cc-pVDZ level were used to analyze the interacti...
Density functional (DFT) calculations at M05-2x/aug-cc-pVDZ level were used to analyze the interacti...
Bromo dimethyl sulfoxide osmium(II) complexes were synthesized: trans-[OsBr2(dmso-S)4] (1) was obtai...
Structural parameters of free and metal coordinated sulfoxides are reviewed and updated average valu...
The title compound, C 2 H 6 OS, is a high melting, polar and aprotic solvent widely used in org...
Osmium is the most rare and scattered element of platinum group metals. Dimethyl sulfoxide complexes...
The reactions between MoCl5and 1–2 equiv. of a selection of sulfoxides at room temperature in dichlo...
The highly unusual Mo(VI) thioether complexes [MoO2X2(L-L)] (X = Cl or Br; L-L = MeS(CH2)(2)SMe or E...
By using accurate density functional theory calculations, we have studied the cluster complexes of a...
The title compound was prepared by base hydrolysis of (p-MeOC6H4)2SeCl2 in water and isolated as the...