Studies in sesquiterpenes-LVI : Isolongifolene (part 7): mechanism of rearrangement of longifolene to isolongifolene-II

Yadav, J. S.
Soman, R.
Sobti, R. R.
Nayak, U. R.
Dev, Sukh

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Publication date

January 1980

DOI

10.1016/0040-4020(80)80099-8

Publisher

Elsevier Science

Abstract

The question of possible neutral intermediates which may lie on the reaction pathway in going from longifolene to isolongifolene has been investigated using BF3·Et2O-AcOD and D3PO4-dioxane, as reagents. It has been found that longicyclene is not an obligatory intermediate. The mode of cleavage of cyclopropane ring in longicyclene has been investigated

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Studies in sesquiterpenes-LVI : Isolongifolene (part 7): mechanism of rearrangement of longifolene to isolongifolene-II

Abstract

Extracted data

Studies in sesquiterpenes-LVI : Isolongifolene (part 7): mechanism of rearrangement of longifolene to isolongifolene-II

Abstract

Extracted data

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